Syntheses, Crystal Structures and Properties of Transition Metal Complexes Based on Pyridine-2,5-dicarboxylic Acid or Thiophene-2,5-dicarboxylic Acid Ligand

被引：3
|
作者：
Han Jia-Xing [1 ]
Liu Zheng [1 ]
Liang Chu-Xin [1 ]
Tang Qun [1 ]
Li Qing-Wei [1 ]
Zhang Shu-Fen [1 ,2 ]
机构：
[1] Guilin Univ Technol, Coll Chem & Bioengn, Guangxi Key Lab Electrochem & Magnetochem Funct M, Guilin 541004, Guangxi, Peoples R China
[2] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Liaoning, Peoples R China
来源：
CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2019年 / 35卷 / 04期
关键词：
heterocyclic carboxyl ligand; transition metal complex; crystal structure; property; OXIDATIVE DESULFURIZATION; NANOPARTICLES; QUECHERS;
D O I：
10.11862/CJIC.2019.069
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Three transition metal coordination polymer materials were successfully synthesized by solvothermal method with the main ligand 2,5-pyridinedicarboxylic acid (H2L1) or thiophene 2,5-dicarboxylic acid (H2L2), and co-ligand 4,4'-bipyridyl (4,4'-bipy) or 1,10-phenanthroline (phen). The complexes were characterized by X-ray single crystal diffraction, infrared spectroscopy (IR), fluorescence spectroscopy (FL) and thermogravimetric analysis (TG/DTG). The analysis of single crystal structure shows that all complexes belong to monoclinic system. Complexes 1 and 2 crystalize in P (1) over bar space group, and complex 3 crystalizes in P2/n. Complex 1 and complex 3 are zero-dimensional dinuclear small molecules, and complex 2 has a two-dimensional network structure. CCDC: 1508171, 1; 1508172, 2; 1508114, 3.
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页码：605 / 612
页数：8
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