Synthesis and Surface Properties of N,N-Dimethyl-N-dodecyl Polyoxyethylene Amine-Based Surfactants: Amine Oxide, Betaine and Sulfobetaine

被引：11

作者：

Hou, Liya ^{[1
]}

Zhang, Huinian ^{[1
]}

Chen, Hui ^{[1
]}

Xia, Qibo ^{[1
]}

Huang, Dongyang ^{[1
]}

Meng, Li ^{[1
]}

Liu, Xuefeng ^{[2
]}

机构：

[1] Jiangnan Univ, Sch Chem & Mat Engn, Wuxi 214122, Peoples R China

[2] Jiangnan Univ, Sch Chem & Mat Engn, Minist Educ, Key Lab Food Colloids & Biotechnol, Wuxi 214122, Peoples R China

来源：

JOURNAL OF SURFACTANTS AND DETERGENTS | 2014年 / 17卷 / 03期

基金：

中国国家自然科学基金;

关键词：

Hybrid surfactant; N; N-Dimethyl-Ndodecyl polyoxyethylene (3) amine; Amine oxide; Betaine; Sulfobetaine; BEHAVIOR; WATER;

D O I：

10.1007/s11743-013-1540-7

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Nonionic-zwitterionic hybrid surfactants, namely N,N-dimethyl-N-dodecyl polyoxyethylene (3) amine oxide, and the corresponding betaine and/or sulfobetaine, have been synthesized. Their molecule structures were characterized by means of electrospray ionization mass spectrometry and H-1 nuclear magnetic resonance. Compared to the structurally related conventional amine oxide, betaine and sulfobetaine, the critical micelle concentrations of the three hybrid surfactants are one order of magnitude smaller than those of traditional ones. The polyoxyethylene segment between the hydrophilic head group and the hydrophobic tail makes the surface activities of the hybrid surfactants superior to their structure-related counterparts.

引用

页码：403 / 408

页数：6

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