Processing Pine Wood into Vanillin and Glucose by Sequential Catalytic Oxidation and Enzymatic Hydrolysis

被引：40

作者：

Tarabanko, Valery E. ^{[1
,2
]}

Kaygorodov, Konstantin L. ^{[1
]}

Skiba, Ekaterina A. ^{[3
]}

Tarabanko, Nikolay ^{[1
]}

Chelbina, Yulia V. ^{[1
]}

Baybakova, Olga V. ^{[3
]}

Kuznetsov, Boris N. ^{[1
,2
]}

Djakovitch, Laurent ^{[4
]}

机构：

[1] Russian Acad Sci, Siberian Branch, Inst Chem & Chem Technol, 50-24 Akademgorodok St, Krasnoyarsk 660036, Russia

[2] Siberian Fed Univ, Krasnoyarsk, Russia

[3] Russian Acad Sci, Siberian Branch, Inst Problems Chem & Energet Technol, Biisk, Russia

[4] Inst Rech Catalyse & Environm Lyon IRCELYON, Villeurbanne, France

来源：

JOURNAL OF WOOD CHEMISTRY AND TECHNOLOGY | 2017年 / 37卷 / 01期

基金：

俄罗斯基础研究基金会;

关键词：

Vanillin; pine wood; lignin; cellulose; enzymatic hydrolysis; CELLULOSE CRYSTALLINITY; ALKALINE MEDIA; WET OXIDATION; WHEAT-STRAW; LIGNIN; ETHANOL; OXYGEN; SYRINGALDEHYDE; VALORIZATION; CHEMICALS;

D O I：

10.1080/02773813.2016.1235583

中图分类号：

TB3 [工程材料学]; TS [轻工业、手工业、生活服务业];

学科分类号：

0805 ; 080502 ; 0822 ;

摘要：

Extractive-free pine wood was processed into vanillin (up to 18wt.% of the initial lignin) and cellulose (typically 84-93% of the initial amount in the wood) by one-step catalytic oxidation followed by enzymatic hydrolysis of the resulting cellulose into glucose (reducing sugar yield up to 70% based on the post-oxidation cellulose). Correlation between the cellulose conversion in hydrolysis and the lignin content in the post-oxidation lignocellulosic material was established, which follows the general trend for the products of various delignification methods. The obtained results demonstrate the practical possibility of efficient two-step processing of wood into vanillin and glucose.

引用

页码：43 / 51

页数：9

共 35 条

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