C-H bond halogenation catalyzed or mediated by copper: an overview

被引:52
作者
Hao, Wenyan
Liu, Yunyun [1 ]
机构
[1] Jiangxi Normal Univ, Minist Educ, Key Lab Funct Small Organ Mol, Nanchang 330022, Peoples R China
来源
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY | 2015年 / 11卷
关键词
C(sp(2))-H bond; C(sp(3))-H bond; copper; halogenation; CROSS-COUPLING REACTIONS; DEHYDROGENATIVE FUNCTIONALIZATION; OXIDATIVE FUNCTIONALIZATION; REGIOSELECTIVE HALOGENATION; LITHIUM HALIDES; MILD CONDITIONS; PALLADIUM; CHLORINATION; IODINATION; PHENOLS;
D O I
10.3762/bjoc.11.230
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Carbon-halogen (C-X) bonds are amongst the most fundamental groups in organic synthesis, they are frequently and widely employed in the synthesis of numerous organic products. The generation of a C-X bond, therefore, constitutes an issue of universal interest. Herein, the research advances on the copper-catalyzed and mediated C-X (X = F, Cl, Br, I) bond formation via direct C-H bond transformation is reviewed.
引用
收藏
页码:2132 / 2144
页数:13
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