An in situ self-assembled Cu4I4-MOF-based mixed matrix membrane: a highly sensitive and selective naked-eye sensor for gaseous HCl

被引:105
作者
Zhao, Chao-Wei [1 ]
Ma, Jian-Ping [1 ]
Liu, Qi-Kui [1 ]
Wang, Xue-Ru [1 ]
Liu, Yi [1 ]
Yang, Jing [1 ]
Yang, Jia-Shi [1 ]
Dong, Yu-Bin [1 ]
机构
[1] Shandong Normal Univ, Coll Chem Chem Engn & Mat Sci, Collaborat Innovat Ctr Functionalized Probes Chem, Key Lab Mol & Nano Probes,Minist Educ, Jinan 250014, Peoples R China
关键词
METAL-ORGANIC FRAMEWORK; GAS SENSORS; VOLATILE; BEHAVIOR; FILM;
D O I
10.1039/c6cc00189k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The Cu4I4-MOF-based mixed matrix membranes (MMMs) can be readily prepared by one-step in situ self-assembly of a tri-armed oxadiazole-bridged ligand and CuI in polymer binder solution under ambient conditions. The visual and luminescent HCl(g) sensing detecting limits of the resulting Cu4I4-MOF-based MMMs are 3.2 and 1.6 ppb, respectively, and the response time is less than 1 min.
引用
收藏
页码:5238 / 5241
页数:4
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