Electro-Optical Parameters with Adverse Order of 10CB Liquid Crystal Molecules Studied under the Influence of an External High Electric Field: A Theoretical Approach

被引:1
作者
Chaudhary, Shivani [1 ]
Kumar, Narinder [1 ]
Singh, Pawan [1 ]
Thapa, Khem B. [1 ]
Kumar, Devesh [1 ]
机构
[1] Babasaheb Bhimrao Ambedkar Univ, Sch Phys & Decis Sci, Dept Phys, Raebareli Rd, Lucknow 226025, Uttar Pradesh, India
来源
JORDAN JOURNAL OF PHYSICS | 2021年 / 14卷 / 01期
关键词
10CB; Electric field; Electro-optical effect; Spectroscopy; Density functional theory (DFT);
D O I
10.47011/14.1.8
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The 10CB liquid crystal (LC) at the higher electric field has a negative-order parameter. The 10CB LC has a definite order that maintains smectic phase stability. 10CB LC has supported the isotropic phase stability at an elevated external electric field and exhibited an unfavorable orientation of the order parameter. At the more upper electric field, the director angle (.) fluctuated and contained. less than 90 degrees. The negative orientation of the order parameter and the large absorption anisotropy enhanced the optical birefringence with a reversal of sign. The negative-order parameter responsible for the IR absorbance has increased instead of reduction. The 10CB liquid crystal is a member of the cyano biphenyl series; therefore, the dipolar strength is maximum contributed to by the C-H atom asymmetric stretching of the alkyl chain length. The 10CB LC has a large bandgap (3.60 eV).
引用
收藏
页码:79 / 87
页数:9
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