The Route to Phosphabenzene and Beyond

被引：9

作者：

Ashe, Arthur J., III ^{[1
]}

机构：

[1] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2016年 / 05期

关键词：

Aromaticity; Group; 15; elements; Heterocycles; pi-Bonding; QUADRUPOLE COUPLING-CONSTANTS; MICROWAVE-SPECTRUM; ELECTRON-DIFFRACTION; MOLECULAR-STRUCTURE; DIPOLE-MOMENT; ARSABENZENE; STIBABENZENE; BISMABENZENE; 9-ARSAANTHRACENE; HETEROBENZENES;

D O I：

10.1002/ejic.201600007

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This article presents the background of the author's synthesis of phosphabenzene in 1971. It also expands to tell the story behind the syntheses of the heavier group 15 heterobenzenes: arsabenzene, stibabenzene, and bismabenzene, which were prepared nearly at the same time and by a largely similar route.

引用

页码：572 / 574

页数：3

共 25 条

[1]

Ashe A.J., 1970, J AM CHEM SOC, V92, P1233, DOI DOI 10.1021/JA00708A021

[2]

ASHE AJ, 1976, TETRAHEDRON LETT, P415

[3]

ASHE AJ, 1982, TOP CURR CHEM, V105, P125

[4] 1-PHENYLBORABENZENE ANION [J].

ASHE, AJ ;

SHU, P .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (07) :1804-&

[5] GROUP-5 HETEROBENZENES [J].

ASHE, AJ .

ACCOUNTS OF CHEMICAL RESEARCH, 1978, 11 (04) :153-157

[6] STIBABENZENE [J].

ASHE, AJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (24) :6690-&

[7] BISMABENZENE - REACTION OF GROUP V HETEROAROMATIC-COMPOUNDS WITH HEXAFLUOROBUTYNE [J].

ASHE, AJ ;

GORDON, MD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (21) :7596-&

[8]

ASHE AJ, 1970, TETRAHEDRON LETT, P2105

[9] NUCLEAR MAGNETIC-RESONANCE SPECTRA OF PHOSPHABENZENE, ARSABENZENE, AND STIBABENZENE [J].

ASHE, AJ ;

SHARP, RR ;

TOLAN, JW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (18) :5451-5456

[10] PHOSPHABENZENE AND ARSABENZENE [J].

ASHE, AJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (13) :3293-&

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