Morphology, thermal and mechanical performances of SR composites containing sepiolite and HGMs as binary fillers

被引:7
作者
Huo, Shanshan [1 ]
Wang, Jinwei [1 ]
Wu, Xinyu [1 ]
机构
[1] Univ Sci & Technol Beijing, Inst Adv Mat & Technol, Beijing 100083, Peoples R China
关键词
binary fillers; polymer matrix composite; silicone rubber; thermal properties; PHYSICAL-PROPERTIES; MATRIX COMPOSITES; GLASS; NANOCOMPOSITES; MICROSPHERES; DENSITY; FIBERS; RESINS; FOAMS;
D O I
10.1515/polyeng-2015-0442
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Binary fillers-filled silicone rubber (SR) matrix composites are prepared to improve the thermal and mechanical properties of SR as a lightweight thermal insulating material. Sepiolite and hollow glass microspheres (HGMs) can be evenly dispersed in SR matrix to obtain SR/sepiolite/HGM composites with superior performances at amounts of around 7.5 parts per hundreds of rubber (phr) and 20 phr, respectively, as observed from scanning electron microscopy (SEM). The density of the composites increases slightly with the addition of sepiolite in a linear trend, while the addition of HGMs results in the abrupt reduction in density lower than 0.7 g/cm(3). Sepiolite exhibits a strengthening effect in the SR matrix; however, the addition of HGMs in this matrix slightly enhances the stress of the composite; its maximum elongation at break can increase up to 300%. The addition of sepiolite and HGMs improves the initial decomposition temperatures of SR composites a little; the excellent thermal insulating effect provided by HGMs is further verified by their significant decrease in thermal conductivity at 200 degrees C, providing the facts that these SR/sepiolite/HGM composites can be used as lightweight materials for thermal insulating purposes.
引用
收藏
页码:197 / 204
页数:8
相关论文
共 24 条
[1]   An investigation of dynamic mechanical, thermal, and electrical properties of housing materials for outdoor polymeric insulators [J].
Ehsani, M ;
Borsi, H ;
Gockenbach, E ;
Morshedian, J ;
Bakhshandeh, GR .
EUROPEAN POLYMER JOURNAL, 2004, 40 (11) :2495-2503
[2]   Tensile properties of glass microballoon-epoxy resin syntactic foams [J].
Gupta, Nikhil ;
Nagorny, Ruslan .
JOURNAL OF APPLIED POLYMER SCIENCE, 2006, 102 (02) :1254-1261
[3]   High Thermoelectric Performance in Non-Toxic Earth-Abundant Copper Sulfide [J].
He, Ying ;
Day, Tristan ;
Zhang, Tiansong ;
Liu, Huili ;
Shi, Xun ;
Chen, Lidong ;
Snyder, G. Jeffrey .
ADVANCED MATERIALS, 2014, 26 (23) :3974-3978
[4]   In situ formed silica particles in rubber vulcanizate by the sol-gel method [J].
Ikeda, Y ;
Kohjiya, S .
POLYMER, 1997, 38 (17) :4417-4423
[5]   Clay modification and its effect on the physical properties of silicone rubber/clay composites [J].
Kim, Eung-Soo ;
Kim, Eun Jeong ;
Lee, Tae Hwa ;
Yoon, Jin-San .
JOURNAL OF APPLIED POLYMER SCIENCE, 2012, 125 :E298-E304
[6]   Preparation and characterization of hollow glass microsphere reinforced poly(butylene succinate) composites [J].
Li, Jiwei ;
Luo, Xuegang ;
Lin, Xiaoyan .
MATERIALS & DESIGN, 2013, 46 :902-909
[7]   Impact fracture toughness of hollow glass bead-filled polypropylene composites [J].
Liang, Ji-Zhao .
JOURNAL OF MATERIALS SCIENCE, 2007, 42 (03) :841-846
[8]  
Liu P, 2009, J APPL POLYM SCI, V132, P41619
[9]   Exploring composites based on PPO blend as ablative thermal protection systems - Part I: The role of layered fillers [J].
Lombardi, M. ;
Fino, P. ;
Malucelli, G. ;
Montanaro, L. .
COMPOSITE STRUCTURES, 2012, 94 (03) :1067-1074
[10]   Development of expanded graphite filled natural rubber vulcanizates in presence and absence of carbon black: Mechanical, thermal and morphological properties [J].
Malas, Asish ;
Das, Chapal Kumar ;
Das, Amit ;
Heinrich, Gert .
MATERIALS & DESIGN, 2012, 39 :410-417