Combustion calorimetry and low-temperature X-ray diffraction of steroid hormone

被引：8

作者：

Knyazev, Alexander V. ^{[1
]}

Smirnova, Nataliya N. ^{[1
]}

Shipilova, Anastasiya S. ^{[1
]}

Larina, Vera N. ^{[1
]}

Gusarova, Ekaterina V. ^{[1
]}

Knyazeva, Svetlana S. ^{[1
]}

机构：

[1] Lobachevsky State Univ Nizhni Novgorod, Gagarin Prospekt 23-2, Nizhnii Novgorod 603950, Russia

来源：

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 2016年 / 123卷 / 03期

关键词：

Hydrocortisone acetate; Hormone; Combustion calorimetry; Thermodynamic functions; Low-temperature X-ray diffraction; THERMODYNAMIC PROPERTIES; HYDROCORTISONE ACETATE;

D O I：

10.1007/s10973-015-4836-1

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The energy of combustion of the hydrocortisone acetate has been measured at 298.15 K by combustion calorimetry (in a calorimeter with a static bomb and an isothermal shield). The enthalpy of combustion Delta(c) HA degrees and the enthalpy of formation Delta(f) HA degrees of the hydrocortisone acetate from simple substances at T = 298.15 K and p = 0.1 MPa have been calculated. The thermochemical analysis of the acylation reaction of hydrocortisone into hydrocortisone acetate was made. The low-temperature X-ray diffraction was used for the determination of coefficients of thermal expansion.

引用

页码：2201 / 2206

页数：6

共 50 条

[41] Structures of quaternary chromium silicides revealed by a combination of resonant X-ray diffraction and ab initio calculations [J].

Brix, Florian ;

Gaudry, Emilie ;

Francois, Michel ;

Elkaim, Erik ;

Desgranges, Clara ;

Sallot, Pierre ;

Mathieu, Stephane ;

Vilasi, Michel .

INTERMETALLICS, 2019, 105 :130-138

[42] Tin (Sn) at high pressure: Review, X-ray diffraction, DFT calculations, and Gibbs energy modeling [J].

Deffrennes, Guillaume ;

Faure, Philippe ;

Bottin, Francois ;

Joubert, Jean-Marc ;

Oudot, Benoit .

JOURNAL OF ALLOYS AND COMPOUNDS, 2022, 919

[43] Thermodynamic characteristics of a natural zinc silicate hemimorphiteResearches by the method of low-temperature adiabatic calorimetry and quantum chemical computation of vibrational states [J].

M. R. Bissengaliyeva ;

N. S. Bekturganov ;

D. B. Gogol .

Journal of Thermal Analysis and Calorimetry, 2010, 101 :49-58

[44] Investigation of cobalt (1,10-phenanthroline)-bis-(3,6-di-tert-butyl-o-benzosemiquinolate) by X-ray diffraction, IR and ESR spectroscopy, magnetochemistry, and precision calorimetry [J].

Bubnov, M. P. ;

Skorodumova, N. A. ;

Bogomyakov, A. S. ;

Romanenko, G. V. ;

Arapova, A. V. ;

Kozhanov, K. A. ;

Smirnova, N. N. ;

Abakumov, G. A. ;

Cherkasov, V. K. .

RUSSIAN CHEMICAL BULLETIN, 2011, 60 (03) :449-455

[45] Synthesis of Silver Nano-cubes and Study of Their Elastic Properties Using X-Ray Diffraction Line Broadening [J].

Sarkar, Sumit ;

Das, Ratan .

JOURNAL OF NONDESTRUCTIVE EVALUATION, 2019, 38 (01)

[46] Study of Bursa L6 ordinary chondrite by X-ray diffraction, magnetization measurements, and Mossbauer spectroscopy [J].

Maksimova, Alevtina A. ;

Petrova, Evgeniya V. ;

Chukin, Andrey V. ;

Unsalan, Ozan ;

Szabo, Abel ;

Dankhazi, Zoltan ;

Felner, Israel ;

Zamyatin, Dmitry A. ;

Kuzmann, Erno ;

Homonnay, Zoltan ;

Oshtrakh, Michael I. .

METEORITICS & PLANETARY SCIENCE, 2020, 55 (12) :2780-2793

[47] Copper complexation and solubility in high-temperature hydrothermal fluids: A combined study by Raman, X-ray fluorescence, and X-ray absorption spectroscopies and ab initio molecular dynamics simulations [J].

Schmidt, Christian ;

Watenphul, Anke ;

Jahn, Sandro ;

Schaepan, Ilona ;

Scholten, Lea ;

Newville, Matthew G. ;

Lanzirotti, Antonio .

CHEMICAL GEOLOGY, 2018, 494 :69-79

[48] Dimorphism of RF3 (R = La-Nd) crystals based on the data of X-ray diffraction studies [J].

Bolotina, N. B. ;

Chernaya, T. S. ;

Verin, I. A. ;

Khrykina, O. N. ;

Sobolev, B. P. .

CRYSTALLOGRAPHY REPORTS, 2016, 61 (01) :29-34

[49] The experimental incorporation of Fe into talc: a study using X-ray diffraction, Fourier transform infrared spectroscopy, and Mossbauer spectroscopy [J].

Corona, Juan Carlos ;

Jenkins, David M. ;

Dyar, M. Darby .

CONTRIBUTIONS TO MINERALOGY AND PETROLOGY, 2015, 170 (03)

[50] Redetermination of the thermodynamic properties of the solid-solid transition of adamantane by adiabatic calorimetry to investigate the suitability as a reference material for low-temperature DSC-calibration [J].

van Ekeren, P. J. ;

van Genderen, A. C. G. ;

van den Berg, G. J. K. .

THERMOCHIMICA ACTA, 2006, 446 (1-2) :33-35

← 1 2 3 4 5 →