Combustion calorimetry and low-temperature X-ray diffraction of steroid hormone

被引：8

作者：

Knyazev, Alexander V. ^{[1
]}

Smirnova, Nataliya N. ^{[1
]}

Shipilova, Anastasiya S. ^{[1
]}

Larina, Vera N. ^{[1
]}

Gusarova, Ekaterina V. ^{[1
]}

Knyazeva, Svetlana S. ^{[1
]}

机构：

[1] Lobachevsky State Univ Nizhni Novgorod, Gagarin Prospekt 23-2, Nizhnii Novgorod 603950, Russia

来源：

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 2016年 / 123卷 / 03期

关键词：

Hydrocortisone acetate; Hormone; Combustion calorimetry; Thermodynamic functions; Low-temperature X-ray diffraction; THERMODYNAMIC PROPERTIES; HYDROCORTISONE ACETATE;

D O I：

10.1007/s10973-015-4836-1

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The energy of combustion of the hydrocortisone acetate has been measured at 298.15 K by combustion calorimetry (in a calorimeter with a static bomb and an isothermal shield). The enthalpy of combustion Delta(c) HA degrees and the enthalpy of formation Delta(f) HA degrees of the hydrocortisone acetate from simple substances at T = 298.15 K and p = 0.1 MPa have been calculated. The thermochemical analysis of the acylation reaction of hydrocortisone into hydrocortisone acetate was made. The low-temperature X-ray diffraction was used for the determination of coefficients of thermal expansion.

引用

页码：2201 / 2206

页数：6

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