Experimental Investigation of CS2 Extraction to Enhance the Permeability of Coal

被引:22
作者
Zhang, Zhen [1 ]
Liu, Gaofeng [1 ,2 ,3 ]
Cao, Yunxing [1 ,3 ]
Lin, Jia [2 ]
Jin, Yi [1 ,3 ]
Xian, Baoan [1 ,3 ]
Lv, Runsheng [2 ,3 ]
Zhang, Zhou [1 ,3 ]
机构
[1] Henan Polytech Univ, Gas Geol & Engn Res Ctr, Jiaozuo 454000, Henan, Peoples R China
[2] Univ Wollongong, Sch Civil Min & Environm Engn, Wollongong, NSW 2500, Australia
[3] Henan Polytech Univ, Collaborat Innovat Ctr Coalbed Methane & Shale Ga, Jiaozuo 454000, Henan, Peoples R China
关键词
Coalbed methane; CS2; extraction; Enhancing permeability; Industrial computed tomography (CT); ADSORPTION CAPACITY; METHANE DEVELOPMENT; CHEMICAL-STRUCTURE; STRUCTURAL-CHANGES; BITUMINOUS COALS; EFFECTIVE STRESS; ANTHRACITE COAL; MOLECULAR-MODEL; PORE STRUCTURE; RANK COALS;
D O I
10.1007/s11242-021-01546-w
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
To examine the permeability enhancement effect of the carbon disulfide (CS2) extraction on block coal samples, in this study, different cylindrical samples of anthracite coal were selected to conduct CS2 extraction experiments. Comprehensive measurement techniques, including Fourier transform infrared spectroscopy, X-ray diffraction, low-temperature nitrogen adsorption, industrial computed tomography, and permeability measurements, were employed to analyze the variations of in the chemical structure, microcrystalline structure, pore-fracture structure, and coal permeability before and after the CS2 extraction treatment. The results showed that CS2 extraction can improve the connectivity of multi-scale migration channels, with which the coal permeability can be enhanced. Also, it was found that the permeability enhancement performance by the CS2 extraction is related to the coal anisotropy, as the coal permeability in the vertical bedding direction is smaller than that in the parallel bedding direction before and after CS2 extraction. Also, the CS2 extraction had a time effect on enhancing the coal permeability, and the permeability enhancement was more significant after a longer period of CS2 treatment. It can be predicted that the permeability can be enhanced up to more than 1 mD when the extraction time exceeds 6 h. Also, we concluded that CS2 fracturing is worth exploring by the on-going studies to enhance the permeability and CBM recovery in low-permeability reservoirs.
引用
收藏
页码:899 / 922
页数:24
相关论文
共 87 条
[1]   Phase states of methane in fossil coals [J].
Alexeev, AD ;
Vasylenko, TA ;
Ul'yanova, EV .
SOLID STATE COMMUNICATIONS, 2004, 130 (10) :669-673
[2]   Investigating the Effects of Seepage-Pores and Fractures on Coal Permeability by Fractal Analysis [J].
Cai, Yidong ;
Liu, Dameng ;
Pan, Zhejun ;
Che, Yao ;
Liu, Zhihua .
TRANSPORT IN POROUS MEDIA, 2016, 111 (02) :479-497
[3]   Pore structure and its impact on CH4 adsorption capacity and flow capability of bituminous and subbituminous coals from Northeast China [J].
Cai, Yidong ;
Liu, Dameng ;
Pan, Zhejun ;
Yao, Yanbin ;
Li, Junqian ;
Qiu, Yongkai .
FUEL, 2013, 103 :258-268
[4]   CO2 gas fracturing: A novel reservoir stimulation technology in low permeability gassy coal seams [J].
Cao, Yunxing ;
Zhang, Junsheng ;
Zhai, Hong ;
Fu, Guoting ;
Tian, Lin ;
Liu, Shimin .
FUEL, 2017, 203 :197-207
[5]   A molecular model for Illinois No. 6 Argonne Premium coal: Moving toward capturing the continuum structure [J].
Castro-Marcano, Fidel ;
Lobodin, Vladislav V. ;
Rodgers, Ryan P. ;
McKenna, Amy M. ;
Marshall, Alan G. ;
Mathews, Jonathan P. .
FUEL, 2012, 95 (01) :35-49
[6]  
Chen P., 2001, J CHINA COAL SOC, V26, P552
[7]   Changes in Pore Structure of Coal Caused by CS2 Treatment and Its Methane Adsorption Response [J].
Chen, Run ;
Qin, Yong ;
Zhang, Pengfei ;
Wang, Youyang .
GEOFLUIDS, 2018,
[8]   The Evolution of Parameters During CBM Drainage in Different Regions [J].
Chen, Yuexia ;
Xu, Jiang ;
Chu, Tingxiang ;
Peng, Shoujian ;
Zhang, Chaolin ;
Wang, Mingyuan .
TRANSPORT IN POROUS MEDIA, 2017, 120 (01) :83-100
[9]   High-resolution X-ray computed tomography in geosciences: A review of the current technology and applications [J].
Cnudde, V. ;
Boone, M. N. .
EARTH-SCIENCE REVIEWS, 2013, 123 :1-17
[10]   Coalbed methane sorption related to coal composition [J].
Crosdale, PJ ;
Beamish, BB ;
Valix, M .
INTERNATIONAL JOURNAL OF COAL GEOLOGY, 1998, 35 (1-4) :147-158