Reducing CO2 with Stable Covalent Organic Frameworks

被引：39

作者：

Lin, Rui-Biao ^{[1
]}

Chen, Banglin ^{[1
]}

机构：

[1] Univ Texas San Antonio, Dept Chem, San Antonio, TX 78249 USA

来源：

JOULE | 2018年 / 2卷 / 06期

关键词：

CATALYSTS; REDUCTION;

D O I：

10.1016/j.joule.2018.05.017

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Covalent organic frameworks (COFs) are highly desirable for electrocatalytic applications but not fully explored yet because of their poor stability. In a recently published paper in Chem, Liu et al. describe an approach to construct chemically stable COFs, involving quantitative linkage conversion from imine COFs, and for co-catalysis of electrochemical CO2 reduction by virtue of the resultant amine sites. The reported amine COF/Ag electrode shows enhanced catalytic selectivity. This work provides a new way to access chemically stable COFs for electrochemical catalysts.

引用

页码：1030 / 1032

页数：4

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