Enabling Catalytic Ketone Hydrogenation by Frustrated Lewis Pairs

被引：236

作者：

Mahdi, Tayseer ^{[1
]}

Stephan, Douglas W. ^{[1
,2
]}

机构：

[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada

[2] King Abdulaziz Univ, Fac Sci, Dept Chem, Jeddah 21589, Saudi Arabia

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2014年 / 136卷 / 45期

基金：

加拿大自然科学与工程研究理事会;

关键词：

METAL-FREE HYDROGENATION; HETEROLYTIC DIHYDROGEN ACTIVATION; CATIONIC RHODIUM COMPLEXES; ASYMMETRIC TRANSFER HYDROGENATION; HOMOGENEOUS HYDROGENATION; SELECTIVE HYDROGENATION; REDUCTION; CO2; ALDEHYDES; CARBONYL;

D O I：

10.1021/ja508829x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydrogenation of alkyl and aryl ketones using H-2 is catalytically achieved in 18 examples using 5 mol % B(C6F5)(3) in an ethereal solvent. In these cases the borane and ether behave as a frustrated Lewis pair to activate H-2 and effect the reduction.

引用

页码：15809 / 15812

页数：4

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