Thermodynamic interaction parameters of tetra-n-undecylcalix[4]resorcinarenes with selected solvents studied by inverse gas chromatography

被引:7
|
作者
Bialon, M
Hetper, J
Pietraszkiewicz, M
Pietraszkiewicz, O
机构
[1] Opole Univ, Inst Chem, PL-45052 Opole, Poland
[2] Polish Acad Sci, Inst Phys Chem, PL-01224 Warsaw, Poland
关键词
inverse gas chromatography; resorcinarenes; thermodynamic parameters;
D O I
10.1023/B:JIPH.0000031115.72041.e5
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The basic thermodynamic parameters, characterising intermolecular interactions of tetra-n-undecylcalix[4]resorcinarene and its octaacetate derivative with simple organic solutes, were calculated by using the inverse gas chromatography method. Free energy, enthalpy and entropy of sorption were determined.
引用
收藏
页码:69 / 73
页数:5
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