inverse gas chromatography;
resorcinarenes;
thermodynamic parameters;
D O I:
10.1023/B:JIPH.0000031115.72041.e5
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
The basic thermodynamic parameters, characterising intermolecular interactions of tetra-n-undecylcalix[4]resorcinarene and its octaacetate derivative with simple organic solutes, were calculated by using the inverse gas chromatography method. Free energy, enthalpy and entropy of sorption were determined.