Recovery of 60Co and 137Cs with various solid phases from aqueous solutions of different chemical composition

被引:2
作者
Kulyukhin, Sergey A. [1 ]
Kulemin, Vladimir V. [1 ]
Krasavina, Elena P. [1 ]
Rumer, Igor' A. [1 ]
Krapukhin, Vladimir B. [1 ]
Gorbacheva, Margarita P. [1 ]
机构
[1] Russian Acad Sci, Frumkin Inst Phys Chem & Electrochem, 31 Leninskii Prospekt, Moscow 119071, Russia
关键词
Co-60; Cs-137; Coprecipitation; Solid phases; Aqueous solution; COMPLEXES;
D O I
10.1007/s10967-018-5714-7
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Removal of microamounts of Co-60 and Cs-137 from different aqueous solutions, included NPP trap waters and simulated NPP bottom residues, by coprecipitation with various solid phases was studied. It was showed that coprecipitation of Co-60 and Cs-137 with the solid phase of K+, Fe3+, and Ni2+ ferrocyanides formed by adding K-4[Fe(CN)(6)], Fe(NO3)(3), and Ni(NO3)(2) ensures almost 100% removal of both radionuclides from simulated NPP trap waters and more than 99% from simulated NPP bottom residue containing simultaneously up to 400 g l(-1) NaNO3 and 3.4 x 10(-5) mol l(-1) EDTA.
引用
收藏
页码:869 / 884
页数:16
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