Solid-State High-Throughput Screening for Color Tuning of Electrochromic Polymers

被引:29
作者
Alamer, Fahad Alhashmi [1 ]
Otley, Michael T. [2 ,3 ]
Ding, Yujie [2 ,3 ]
Sotzing, Gregory A. [1 ,2 ,3 ]
机构
[1] Univ Connecticut, Dept Phys, Storrs, CT 06269 USA
[2] Univ Connecticut, Dept Chem, Storrs, CT 06269 USA
[3] Univ Connecticut, Polymer Program, Storrs, CT 06269 USA
关键词
OPTOELECTROCHEMICAL PROPERTIES; PHOTOVOLTAIC CELLS; COPOLYMER; 3,4-ETHYLENEDIOXYTHIOPHENE; PYRROLE; BLACK;
D O I
10.1002/adma.201302729
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Diffusion of two monomers and their oxidative copolymerization inside a solid-state gel electrolyte is utilized as a method to match the monomer feed ratio to a color resulting from a conjugated copolymer having a single absorption in the visible region. Here, a combination of two monomers is used to generate a solid-state electrochromic device of any color, except black and green, in the colored state with all other colors going to transmissive sky blue in the bleached state.
引用
收藏
页码:6256 / 6260
页数:5
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