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Optical characteristics and luminescence of amorphous BaTiO3 thin films doped with Eu3+
被引:6
作者:
Lee, K. T.
[1
]
Osman, R. A. M.
[1
]
Poopalan, P.
[1
]
机构:
[1] Univ Malaysia Perlis, Fac Elect Engn Technol, Arau 02600, Perlis, Malaysia
关键词:
Photoluminescence;
Lanthanides;
Amorphous;
Barium titanate;
Thin film;
Phosphor;
RED-EMITTING PHOSPHOR;
PHOTOLUMINESCENCE PROPERTIES;
ENERGY-TRANSFER;
GLASSES;
FLUORESCENCE;
SPECTRA;
D O I:
10.1016/j.jnoncrysol.2020.120515
中图分类号:
TQ174 [陶瓷工业];
TB3 [工程材料学];
学科分类号:
0805 ;
080502 ;
摘要:
Sol-gel spin coated BaTiO3:Eu3+ thin films on fused silica substrate were thermally annealed between 400 degrees C and 800 degrees C. The multilayer films were doped with Eu3+ which was limited to 10 mol % doping concentration. Standard physical and optical characterizations were performed in addition to excitation-emission and UVPL spectroscopy. The films were amorphous at temperatures below 600 degrees C and exhibited stronger luminescence at 613.0 nm (D-5(0) -> F-7(2)) than crystalline films. Optical energy band-gap ranged from 3.825 eV (crystalline) to 4.325 eV (amorphous) and the amorphous films' CIE showed excellent red coordinates whilst red/orange (R/O) asymmetry ratio shows tailored emission color is possible.
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页数:8
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