Investigation on electrochemical characteristics of maltodextrin - methyl cellulose electrolytes

被引:11
作者
Asnawi, A. S. F. M. [1 ]
Hamsan, M. H. [2 ]
Kadir, M. F. Z. [3 ]
Aziz, S. B. [4 ,5 ]
Yusof, Y. M. [1 ]
机构
[1] Univ Kuala Lumpur, Malaysian Inst Chem & Bioengn Technol UniKL MICET, Chem Engn Sect, Alor Gajah 78000, Malacca, Malaysia
[2] Univ Malaya, Inst Grad Studies, Kuala Lumpur, Malaysia
[3] Univ Malaya, Ctr Fdn Studies Sci, Kuala Lumpur, Malaysia
[4] Univ Sulaimani, Coll Sci, Dept Phys, Adv Polymer Mat Res Lab, Qlyasan St, Sulaimani, Kurdistan Regio, Iraq
[5] Komar Univ Sci & Technol, Komar Res Ctr KRC, Sulaimani, Kurdistan Regio, Iraq
关键词
Ammonium bromide; linear sweep voltammetry; maltodextrin; methylcellulose blend; solid polymer electrolyte; transport parameters; X-ray diffraction; BLEND-BASED ELECTROLYTE; BIOPOLYMER ELECTROLYTES; POLYMER ELECTROLYTE; ELECTRICAL-PROPERTIES; CHITOSAN BLEND; DISINTEGRATING TABLETS; TRANSPORT-PROPERTIES; CROSS-LINKING; CONDUCTIVITY; IMPEDANCE;
D O I
10.1080/15421406.2020.1810954
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Methyl cellulose (MC) is well-known as a good candidate to serve as polymer host while maltodextrin (MX) is an interesting polymer to be explored in this field. MX-MC based electrolyte has the highest conductivity of (1.70 +/- 0.69) x 10(-5) S cm(-1) with 25 wt.% NH4Br. The electrolyte exhibits the Arrhenius behavior with E-a value of 0.36 eV. Dielectric analysis verifies the non-Debye behavior of MX-MC-NH4Br electrolytes. Thermogravimetric analysis reveals that the electrolytes are stable until similar to 220 degrees C. From linear sweep voltammetry result, S25 is electrochemically stable up to 1.22 V, which shows the potential for device applications.
引用
收藏
页码:63 / 91
页数:29
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