Synthesis and Structural Characterization of a Cobalt Coordination Polymer Assembled by Bis(4-(1H-benzo[d]imidazol-1-yl)phenyl)methanone and Phthalate

被引:0
作者
Sun, S. -W. [1 ]
Wang, G. -F. [1 ]
Lu, T. -T. [1 ]
机构
[1] Yuncheng Univ, Dept Appl Chem, Yuncheng 044000, Peoples R China
关键词
BIS(4-(1H-IMIDAZOL-1-YL)PHENYL)METHANONE;
D O I
10.1134/S1063774520070238
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
A cobalt coordination polymer with the formula of {[Co(L-1)(pa)]}(n) (1) (L-1 = bis(4-(1H-benzo[d]imidazol-1-yl)phenyl)methanone, H(2)pa = phthalic acid) was synthesized under solvothermal condition. It was characterized by infrared spectroscopy, elemental and single-crystal X-ray diffraction analyses. Crystal 1 is monoclinic, the space group is P2(1)/c with the unit cell parameters a = 8.1394(2), b = 25.7199(5), c = 15.1719(4) angstrom, beta = 117.554(2)degrees, Z = 4; R-1 = 0.0405 and wR(2) = 0.0953 (I > 2 sigma). In 1, [Co-2(pa)(2)] bridged by pa(2-) anions are linked by four adjacent L-1 ligands and form 2D layers.
引用
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页码:1142 / 1144
页数:3
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