Enhancement in Mechanical, Thermal, and Dielectric Properties of Functionalized Graphene Oxide Reinforced Epoxy Composites

被引:15
作者
Kumar, S. M. Suresh [1 ]
Subramanian, K. [1 ]
机构
[1] Anna Univ, Dept Chem, Madras 600025, Tamil Nadu, India
关键词
Composites; Dynamic mechanical properties; FT-IR; Mechanical properties; X-ray; IN-SITU POLYMERIZATION; NANOCOMPOSITES; CONSTANT; FABRICATION; PARTICLES; STRENGTH; FILMS;
D O I
10.1002/adv.21702
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The present work has the objective of fabricating graphene oxide (GO) and amine-functionalized graphene oxide (F-GO) reinforced epoxy composites using the casting method. Epoxy resin was dispersed separately with GO (0.5 wt%) and F-GO (0.5 and 1 wt%), and then the epoxy resin mixture cured with triethylenetetraamine at room temperature. The synthesized GO and F-GO were characterized by FT-IR and Raman spectroscopy. The interfacial interaction of Si in the composite was studied by XPS. The formation of GO and F-GO was confirmed by XRD. The tensile and flexural strength composites were measured using the UTM. The thermal behavior and dynamic mechanical behavior were examined by TGA and DMA. The surface morphology and dielectrical properties were analyzed by SEM, TEM, and impedance analyses. The results obtained from epoxy/F-GO (0.5 wt%) composite revealed higher mechanical and thermal properties than neat epoxy and epoxy/GO composites. (c) 2016 Wiley Periodicals, Inc.
引用
收藏
页码:612 / 621
页数:10
相关论文
共 46 条
[1]   Role of particle cavitation in rubber-toughened epoxies: II. Inter-particle distance [J].
Bagheri, R ;
Pearson, RA .
POLYMER, 2000, 41 (01) :269-276
[2]   In situ preparation of functionalized graphene oxide/epoxy nanocomposites with effective reinforcements [J].
Bao, Chenlu ;
Guo, Yuqiang ;
Song, Lei ;
Kan, Yongchun ;
Qian, Xiaodong ;
Hu, Yuan .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (35) :13290-13298
[3]   Toughened carbon/epoxy composites made by using core/shell particles [J].
Day, RJ ;
Lovell, PA ;
Wazzan, AA .
COMPOSITES SCIENCE AND TECHNOLOGY, 2001, 61 (01) :41-56
[4]   Studies on mechanical, thermal and dynamic mechanical properties of functionalized nanoalumina reinforced sulphone ether linked tetraglycidyl epoxy nanocomposites [J].
Duraibabu, D. ;
Alagar, M. ;
Kumar, S. Ananda .
RSC ADVANCES, 2014, 4 (76) :40132-40140
[5]   Covalent polymer functionalization of graphene nanosheets and mechanical properties of composites [J].
Fang, Ming ;
Wang, Kaigang ;
Lu, Hongbin ;
Yang, Yuliang ;
Nutt, Steven .
JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (38) :7098-7105
[6]   Preparation and properties of thermostable well-functionalized graphene oxide/polyimide composite films with high dielectric constant, low dielectric loss and high strength via in situ polymerization [J].
Fang, Xinliang ;
Liu, Xiaoyun ;
Cui, Zhong-Kai ;
Qian, Jun ;
Pan, Jijia ;
Li, Xinxin ;
Zhuang, Qixin .
JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (18) :10005-10012
[7]   Thermal, electrical, and mechanical properties of polyethylenegraphene nanocomposites obtained by in situ polymerization [J].
Fim, Fabiana de C. ;
Basso, Nara R. S. ;
Graebin, Ana P. ;
Azambuja, Denise S. ;
Galland, Griselda B. .
JOURNAL OF APPLIED POLYMER SCIENCE, 2013, 128 (05) :2630-2637
[8]   The rise of graphene [J].
Geim, A. K. ;
Novoselov, K. S. .
NATURE MATERIALS, 2007, 6 (03) :183-191
[9]   Toward effective and tunable interphases in graphene oxide/epoxy composites by grafting different chain lengths of polyetheramine onto graphene oxide [J].
Guan, Li-Zhi ;
Wan, Yan-Jun ;
Gong, Li-Xiu ;
Yan, Dong ;
Tang, Long-Cheng ;
Wu, Lian-Bin ;
Jiang, Jian-Xiong ;
Lai, Guo-Qiao .
JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (36) :15058-15069
[10]   PREPARATION OF GRAPHITIC OXIDE [J].
HUMMERS, WS ;
OFFEMAN, RE .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (06) :1339-1339