Photophysical properties of Eu3+ and Tb3+-doped ZnAl2O4 phosphors obtained by combustion reaction

被引:87
作者
Barros, B. S.
Melo, P. S.
Kiminami, R. H. G. A. [1 ]
Costa, A. C. F. M.
de Sa, G. F.
Alves, S., Jr.
机构
[1] Univ Fed Campina Grande, Dept Mat Engn, Campina Grande, PB, Brazil
[2] Univ Fed Pernambuco, Dept Fundamental Chem, Rare Earth Lab, BSTR, Recife, PE, Brazil
[3] Univ Fed Sao Carlos, Dept Mat Engn, Sao Carlos, SP, Brazil
关键词
D O I
10.1007/s10853-006-0035-6
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Europium- and terbium-doped zinc aluminate oxide nanocrystals with a spinel structure were successfully prepared by a combustion method, using urea as fuel. The samples thus obtained were characterized by X-ray diffraction, scanning electron microscopy and luminescence spectroscopy. X-ray diffraction results confirmed the formation of ZnAl2O4 spinel phase and a minor amount of ZnO. Our SEM results revealed agglomerates in the shape of irregular plates composed of nanoparticles with dispersed points of second phase in the surface. Powders containing Eu3+ and Tb3+ ions displayed red and green photoluminescence, respectively.
引用
收藏
页码:4744 / 4748
页数:5
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