Auxiliary field theory of polymers with intrinsic curvature

被引:8
作者
Craig, A [1 ]
Terentjev, EM [1 ]
机构
[1] Univ Cambridge, Cavendish Lab, Cambridge CB3 0HE, England
关键词
D O I
10.1021/ma060159h
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
We treat polymer chains with an intrinsic curvature, which we model by a continuum extension of a microscopic model with preferred bending angle. From this model, we obtain a modified form of the mean-field Hamiltonian used to describe semiflexible chains. We then employ an auxiliary field operator to enforce the mean curvature constraint along with a torsional constraint. Using this formalism, we provide analytic results for the tangent-tangent correlator [u( s).u(s')], mean square radius of gyration [S-2], and mean square separation [R-2]. We also obtain approximate results for the force-extension behavior of these chains, and discuss possible extensions to curved polymers with excluded volume and other self-interactions.
引用
收藏
页码:4557 / 4565
页数:9
相关论文
共 45 条
[1]  
BIRSHTEIN TM, 1966, HIGH POLYM SERIES, V22
[2]   DYNAMICS OF A LONG POLYMER BACKBONE [J].
BUGL, P ;
FUJITA, S .
JOURNAL OF CHEMICAL PHYSICS, 1969, 50 (08) :3137-&
[3]   Extension of rod-coil multiblock copolymers and the effect of the helix-coil transition [J].
Buhot, A ;
Halperin, A .
PHYSICAL REVIEW LETTERS, 2000, 84 (10) :2160-2163
[4]   Scaling of dynamics in 2d semi-dilute polymer solutions [J].
Cicuta, P ;
Hopkinson, I .
EUROPHYSICS LETTERS, 2004, 68 (01) :65-71
[5]   Photocontrol of protein conformation in a Langmuir monolayer [J].
Cicuta, P ;
Hopkinson, I ;
Petrov, PG .
JOURNAL OF CHEMICAL PHYSICS, 2001, 115 (21) :9991-9994
[6]  
De Gennes PG., 1979, SCALING CONCEPTS POL
[7]  
DESCLOISEAUX J, 1990, POLYM SOLUTION THEIR
[8]  
DILISI GA, 1993, J PHYS II, V3, P597, DOI 10.1051/jp2:1993153
[9]  
Doi M., 1986, THEORY POLYM DYNAMIC
[10]   STATISTICAL MECHANICS OF POLYMERS WITH EXCLUDED VOLUME [J].
EDWARDS, SF .
PROCEEDINGS OF THE PHYSICAL SOCIETY OF LONDON, 1965, 85 (546P) :613-&