Hierarchical SnO2 Nanostructures Made of Intermingled Ultrathin Nanosheets for Environmental Remediation, Smart Gas Sensor, and Supercapacitor Applications

被引:476
作者
Liu, Yang [1 ,2 ]
Jiao, Yang [1 ,2 ]
Zhang, Zhenglin [1 ,2 ]
Qu, Fengyu [1 ,2 ]
Umar, Ahmad [3 ,4 ]
Wu, Xiang [1 ,2 ]
机构
[1] Harbin Normal Univ, Key Lab Photon & Elect Bandgap Mat, Minist Educ, Harbin 150025, Peoples R China
[2] Harbin Normal Univ, Coll Chem & Chem Engn, Harbin 150025, Peoples R China
[3] Najran Univ, Coll Arts & Sci, PCSED, Najran 11001, Saudi Arabia
[4] Najran Univ, Coll Arts & Sci, Dept Chem, Najran 11001, Saudi Arabia
关键词
SnO2; nanostructures; ultrathin nanosheets; environmental remediation; gas sensor; supercapacitor; OXIDE NANOSTRUCTURES; NANOCRYSTALLINE SNO2; SENSING PERFORMANCE; OPTICAL-PROPERTIES; CRYSTAL-GROWTH; FIELD-EMISSION; ZNO; HETEROSTRUCTURES; NANOWIRES; NANORODS;
D O I
10.1021/am405301v
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
In this paper, the hierarchical SnO2 nanostructures (HTNs) were prepared by a facile hydrothermal process. The prepared HTNs were characterized in detail by various analytical techniques that reveal the well. crystallinity with tetragonal rutile structure of SnO2 for the as-prepared material. By detailed experiments, interestingly, it was observed that the shapes and sizes of as-prepared HTNs could be tailored by varying the precursor concentration and reaction time. The synthesized HTNs were used as the efficient photocatalysts for the photocatalytic degradation of methylene blue (MB) under light illumination which showed almost complete degradation (similar to 99%) of MB dye in 20 min. The observed degradation for MB dye was higher than other commonly used dyes, i.e. methyl orange (MO; 96% in 50 min) and Rhodamine B (RhB; 97% in 40 min.). Further, the prepared HTNs were used as the effective gas sensing material to examine a series of volatile gases, such as ethanol, ammonia, benzene, acetone, toluene, methanol, diethyl ether, and methanol. By the detailed experiments, it was observed that the prepared HTNs exhibited tremendous gas sensing performance toward ethanol. Finally, because of the unique morphology and the fast ion and electron transfer characteristics, the prepared HTNs show excellent supercapacitor performances.
引用
收藏
页码:2174 / 2184
页数:11
相关论文
共 53 条
[1]   Structural characterization of nanocrystalline SnO2 by X-ray and Raman spectroscopy [J].
Abello, L ;
Bochu, B ;
Gaskov, A ;
Koudryavtseva, S ;
Lucazeau, G ;
Roumyantseva, M .
JOURNAL OF SOLID STATE CHEMISTRY, 1998, 135 (01) :78-85
[2]  
Ahmad U., 2010, METAL OXIDE NANOSTRU
[3]   Aggregation-based crystal growth and microstructure development in natural iron oxyhydroxide biomineralization products [J].
Banfield, JF ;
Welch, SA ;
Zhang, HZ ;
Ebert, TT ;
Penn, RL .
SCIENCE, 2000, 289 (5480) :751-754
[4]   Super-hydrophobic tin oxide nanoflowers [J].
Chen, AC ;
Peng, XS ;
Koczkur, K ;
Miller, B .
CHEMICAL COMMUNICATIONS, 2004, (17) :1964-1965
[5]   Nanowires Assembled SnO2 Nanopolyhedrons with Enhanced Gas Sensing Properties [J].
Chen, Di ;
Xu, Jing ;
Xie, Zhong ;
Shen, Guozhen .
ACS APPLIED MATERIALS & INTERFACES, 2011, 3 (06) :2112-2117
[6]   A novel hydrothermal route to synthesize solid SnO2 nanospheres and their photoluminescence property [J].
Chen, H. T. ;
Wu, X. L. ;
Zhang, Y. Y. ;
Zhu, J. ;
Cheng, Y. C. ;
Chu, Paul K. .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2009, 97 (03) :581-585
[7]   SnO2 hollow structures and TiO2 nanosheets for lithium-ion batteries [J].
Chen, Jun Song ;
Archer, Lynden A. ;
Lou, Xiong Wen .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (27) :9912-9924
[8]   Large-scale, solution-phase growth of single-crystalline SnO2 nanorods [J].
Cheng, B ;
Russell, JM ;
Shi, WS ;
Zhang, L ;
Samulski, ET .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (19) :5972-5973
[9]   Self-assembly synthesis of single-crystalline tin oxide nanostructures by a poly(acrylic acid)-assisted solvothermal process [J].
Cheng, Guoe ;
Wang, Jinmin ;
Liu, Xiangwen ;
Huang, Kaixun .
JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (33) :16208-16211
[10]   One-Step Synthesis of the Nanostructured AgI/BiOI Composites with Highly Enhanced Visible-Light Photocatalytic Performances [J].
Cheng, Hefeng ;
Huang, Baibiao ;
Dai, Ying ;
Qin, Xiaoyan ;
Zhang, Xiaoyang .
LANGMUIR, 2010, 26 (09) :6618-6624