The moisture-responsive structural transformation of manganochlorine for water-soluble luminescent switching ink

被引：23

作者：

Lin, Yang-Peng ^{[1
]}

Rao, Lin-Cong ^{[2
]}

Zhao, Ming-Jun ^{[1
]}

Huang, Xiao-Ying ^{[2
]}

Du, Ke-Zhao ^{[1
]}

机构：

[1] Fujian Normal Univ, Fujian Prov Key Lab Polymer Mat, Coll Chem & Mat Sci, Fuzhou 350007, Peoples R China

[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China

来源：

DALTON TRANSACTIONS | 2021年 / 50卷 / 06期

基金：

中国国家自然科学基金;

关键词：

MN2+ IONS; CRYSTAL-STRUCTURE; COMPLEXES; CSMNCL3; SINGLE; EMISSION; HYBRID; CSMNCL3-CENTER-DOT-2H(2)O; FLUORESCENCE; TRANSITIONS;

D O I：

10.1039/d0dt03948a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

CsMnCl3(H2O)(2) (CMCH) has been widely investigated for magnetic and optical applications, including anti-Stokes photoluminescence, microwave absorption, and magnon-assisted optical transitions. Herein, CMCH crystals, which are colorless and transparent (unlike the pink crystals reported previously), were obtained through a unique approach. Consequently, a high-resolution optical absorption spectrum and distinct thermal behavior were observed. The reversible (de)hydration of CMCH being accompanied by photoluminescence switching (mainly in terms of the color temperature) was rationalized using crystal structure analysis. As a result, water-soluble CMCH could be applied as a moisture-responsive luminescent ink. Moreover, density functional theory (DFT) calculations were performed to understand the optical absorption of CMCH.

引用

页码：2001 / 2006

页数：6

共 66 条

[1] Anomalies in microwave absorption in quasi-one-dimensional CsMnCl3•2H2O in a pulsed magnetic field [J].

Anders, AG ;

Kobets, MI .

LOW TEMPERATURE PHYSICS, 1999, 25 (06) :436-439

[2]

[Anonymous], 1994, Luminescent Materials

[3] MAGNETOSTRICTION, THERMAL EXPANSION, AND PHASE TRANSITIONS IN CSMNC13.2H20 [J].

ARON, PR ;

WOOLLAM, JA ;

BUTTERWORTH, GJ .

PHYSICS LETTERS A, 1971, A 35 (06) :422-+

[4] Luminescence of the Mn2+ ion in non-Oh and Td coordination environments: the missing case of square pyramid [J].

Artem'ev, Alexander, V ;

Davydova, Maria P. ;

Berezin, Alexey S. ;

Brel, Valery K. ;

Morgalyuk, Vasilii P. ;

Bagryanskaya, Irina Yu ;

Samsonenko, Denis G. .

DALTON TRANSACTIONS, 2019, 48 (43) :16448-16456

[5] Tuning the Luminescence of Phosphors: Beyond Conventional Chemical Method [J].

Bai, Gongxun ;

Tsang, Ming-Kiu ;

Hao, Jianhua .

ADVANCED OPTICAL MATERIALS, 2015, 3 (04) :431-462

[6] Pyridine-Modulated Mn Ion Emission Properties of C10H12N2MnBr4 and C5H6NMnBr3 Single Crystals [J].

Bai, Xianwei ;

Zhong, Haizheng ;

Chen, Bingkun ;

Chen, Cheng ;

Han, Junbo ;

Zeng, Ruosheng ;

Zou, Bingsuo .

JOURNAL OF PHYSICAL CHEMISTRY C, 2018, 122 (05) :3130-3137

[7] Orange-emitting manganese(II) complexes with chelating phosphine oxides [J].

Bortoluzzi, M. ;

Castro, J. ;

Trave, E. ;

Dallan, D. ;

Favaretto, S. .

INORGANIC CHEMISTRY COMMUNICATIONS, 2018, 90 :105-107

[8] Green-emitting manganese (II) complexes with phosphoramide and phenylphosphonic diamide ligands [J].

Bortoluzzi, Marco ;

Castro, Jesus ;

Enrichi, Francesco ;

Vomiero, Alberto ;

Busato, Marta ;

Huang, Weizhe .

INORGANIC CHEMISTRY COMMUNICATIONS, 2018, 92 :145-150

[9]

Burns R.G., 1993, Mineralogical applications of crystal field theory, Vsecond

[10] Lead-free/rare earth-free Green-light-emitting crystal based on organic-inorganic hybrid [(C10H16N)2][MnBr4] with high emissive quantum yields and large crystal size [J].

Cai, Xing-Wei ;

Zhao, Yu-Yuan ;

Li, Hong ;

Huang, Cui-Ping ;

Zhou, Zhen .

JOURNAL OF MOLECULAR STRUCTURE, 2018, 1161 :262-266

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