Rhodizonate metal complexes with a 2D chairlike M6 metal-organic framework:: [M(C6O6)(bpym)(H2O)•nH2O

被引：21

作者：

Wang, CC ^{[1
]}

Kuo, CT

Chou, PT

Lee, GH

机构：

[1] Soochow Univ, Dept Chem, Taipei 11102, Taiwan

[2] Natl Taiwan Univ, Dept Chem, Taipei 10764, Taiwan

[3] Natl Taiwan Univ, Instrumental Ctr, Taipei 10764, Taiwan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 34期

关键词：

cadmium; coordination modes; manganese; O ligands;

D O I：

10.1002/anie.200460278

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two transition-metal rhodizonate complexes, [M(C6O 6)(bpym)(H2O)]·nH2O (M = Cd, n = 1; M = Mn, n = 2; bpym = 2,2′-bipyrimidine), are reported. Both the rhodizonate and bpym ligands are bis-bidentate ligands (see the Cd example depicted) which chelate the metal ions, thus forming a novel 2D chairlike M6 metal-organic framework.

引用

页码：4507 / 4510

页数：4

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