Rhodizonate metal complexes with a 2D chairlike M6 metal-organic framework:: [M(C6O6)(bpym)(H2O)•nH2O

被引：21
|
作者：
Wang, CC [1 ]
Kuo, CT
Chou, PT
Lee, GH
机构：
[1] Soochow Univ, Dept Chem, Taipei 11102, Taiwan
[2] Natl Taiwan Univ, Dept Chem, Taipei 10764, Taiwan
[3] Natl Taiwan Univ, Instrumental Ctr, Taipei 10764, Taiwan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 34期
关键词：
cadmium; coordination modes; manganese; O ligands;
D O I：
10.1002/anie.200460278
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two transition-metal rhodizonate complexes, [M(C6O 6)(bpym)(H2O)]·nH2O (M = Cd, n = 1; M = Mn, n = 2; bpym = 2,2′-bipyrimidine), are reported. Both the rhodizonate and bpym ligands are bis-bidentate ligands (see the Cd example depicted) which chelate the metal ions, thus forming a novel 2D chairlike M6 metal-organic framework.
引用
收藏
页码：4507 / 4510
页数：4
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