Solvent-Dependent Self-Assembly and Crystal Structures of a Salen-Based Macrocycle

被引：13

作者：

Tominaga, Masahide ^{[1
]}

Takahashi, Eri ^{[1
]}

Ukai, Hiroyuki ^{[1
]}

Ohara, Kazuaki ^{[1
]}

Itoh, Tsutomu ^{[2
]}

Yamaguchi, Kentaro ^{[1
]}

机构：

[1] Tokushima Bunri Univ, Fac Pharmaceut Sci, Kagawa Campus,1314-1 Shido, Sanuki, Kagawa 7692193, Japan

[2] Chiba Univ, Ctr Analyt Instrumentat, Inage Ku, 1-33 Yayoi Cho, Chiba 2638522, Japan

来源：

ORGANIC LETTERS | 2017年 / 19卷 / 07期

关键词：

ASYMMETRIC CATALYSIS; ORGANIC-MOLECULES; COMPLEXES; ORGANIZATION; AGGREGATION; FRAMEWORKS; VESICLES; METAL; WATER;

D O I：

10.1021/acs.orglett.7b00264

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A salen-based macrocycle possessing, adamantane units was constructed from two ethylenediamine and two disubstituted adamantane-bearing salicylaldehyde components. The addition of methanol to a tetrahydrofuran solution of the macrocycle afforded the crystals via hollow spherical and fused aggregates, and X-ray crystallographic analysis showed that the macrocycle had a rhomboidal structure; The use of chloroform instead of methanol gave the crystals of a square-shaped macrocycle without the formation of self-assembled materials.

引用

页码：1508 / 1511

页数：4

共 49 条

[21] Macrocyclic amphiphiles
Jie, Kecheng
Zhou, Yujuan
Yao, Yong
Huang, Feihe
[J]. CHEMICAL SOCIETY REVIEWS, 2015, 44 (11) : 3568 - 3587
[22] CATALYTIC ASYMMETRIC OXIDATIONS USING OPTICALLY-ACTIVE (SALEN)MANGANESE(III) COMPLEXES AS CATALYSTS
KATSUKI, T
[J]. COORDINATION CHEMISTRY REVIEWS, 1995, 140 : 189 - 214
[23] Reversible Transformation of Helical Coils and Straight Rods in Cylindrical Assembly of Elliptical Macrocycles
Kim, Jung-Keun
Lee, Eunji
Kim, Min-Cheol
Sim, Eunji
Lee, Myongsoo
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (49) : 17768 - 17770
[24] Stimuli-responsive supramolecular nanocapsules from amphiphilic calixarene assembly
Lee, M
Lee, SJ
Jiang, LH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (40) : 12724 - 12725
[25] Chiral macrocycle-catalyzed highly enantioselective phenylacetylene addition to aliphatic and vinyl aldehydes
Li, Zi-Bo
Liu, Tian-Dong
Pu, Lin
[J]. JOURNAL OF ORGANIC CHEMISTRY, 2007, 72 (12) : 4340 - 4343
[26] Cucurbit[6]uril: Organic molecular porous material with permanent porosity, exceptional stability, and acetylene sorption properties
Lim, Soyoung
Kim, Hyunuk
Selvapalam, Narayanan
Kim, Kyung-Jin
Cho, Sung June
Seo, Gon
Kim, Kimoon
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (18) : 3352 - 3355
[27] Synthesis and metalation of novel fluorescent conjugated macrocycles
Ma, C
Lo, A
Abdolmaleki, A
MacLachlan, MJ
[J]. ORGANIC LETTERS, 2004, 6 (21) : 3841 - 3844
[28] Supramolecular assembly and coordination-assisted deaggregation of multimetallic macrocycles
Ma, CTL
MacLachlan, MJ
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (27) : 4178 - 4182
[29] Permanent Porous Materials from Discrete Organic Molecules-Towards Ultra-High Surface Areas
Mastalerz, Michael
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2012, 18 (33) : 10082 - 10091
[30] Pillar-Shaped Macrocyclic Hosts Pillar[n]arenes: New Key Players for Supramolecular Chemistry
Ogoshi, Tomoki
Yamagishi, Tada-aki
Nakamoto, Yoshiaki
[J]. CHEMICAL REVIEWS, 2016, 116 (14) : 7937 - 8002

← 1 2 3 4 5 →