Solvent-Dependent Self-Assembly and Crystal Structures of a Salen-Based Macrocycle

被引：13

作者：

Tominaga, Masahide ^{[1
]}

Takahashi, Eri ^{[1
]}

Ukai, Hiroyuki ^{[1
]}

Ohara, Kazuaki ^{[1
]}

Itoh, Tsutomu ^{[2
]}

Yamaguchi, Kentaro ^{[1
]}

机构：

[1] Tokushima Bunri Univ, Fac Pharmaceut Sci, Kagawa Campus,1314-1 Shido, Sanuki, Kagawa 7692193, Japan

[2] Chiba Univ, Ctr Analyt Instrumentat, Inage Ku, 1-33 Yayoi Cho, Chiba 2638522, Japan

来源：

ORGANIC LETTERS | 2017年 / 19卷 / 07期

关键词：

ASYMMETRIC CATALYSIS; ORGANIC-MOLECULES; COMPLEXES; ORGANIZATION; AGGREGATION; FRAMEWORKS; VESICLES; METAL; WATER;

D O I：

10.1021/acs.orglett.7b00264

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A salen-based macrocycle possessing, adamantane units was constructed from two ethylenediamine and two disubstituted adamantane-bearing salicylaldehyde components. The addition of methanol to a tetrahydrofuran solution of the macrocycle afforded the crystals via hollow spherical and fused aggregates, and X-ray crystallographic analysis showed that the macrocycle had a rhomboidal structure; The use of chloroform instead of methanol gave the crystals of a square-shaped macrocycle without the formation of self-assembled materials.

引用

页码：1508 / 1511

页数：4

共 49 条

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