Multilayers formed by polyelectrolyte-surfactant and related mixtures at the air-water interface

被引：31

作者：

Li, Peixun ^{[1
]}

Penfold, Jeffery ^{[1
]}

Thomas, Robert K. ^{[2
]}

Xu, Hui ^{[3
]}

机构：

[1] Rutherford Appleton Lab, STFC, Didcot OX11 0RA, Oxon, England

[2] Phys & Theoret Chem Lab, South Parks Rd, Oxford OX1 3QZ, England

[3] KLK OLEO, Room 1603,16th Floor,LZY Tower,4711 Jiao Tong Rd, Shanghai 200331, Peoples R China

来源：

ADVANCES IN COLLOID AND INTERFACE SCIENCE | 2019年 / 269卷

关键词：

SODIUM DODECYL-SULFATE; OPPOSITELY CHARGED POLYELECTROLYTE; METHYL-ESTER SULFONATE; AIR/WATER INTERFACE; ANIONIC SURFACTANT; AEROSOL-OT; IONIC SURFACTANT; AQUEOUS-SOLUTION; PHASE-BEHAVIOR; TRIMETHYLAMMONIUM BROMIDE;

D O I：

10.1016/j.cis.2019.04.002

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The structure and occurrence of multilayered adsorption at the air-water interface of surfactants in combination with other oppositely charged species is reviewed. The main species that trigger multilayer formation are multiply charged metal, oligo- and polyions. The structures vary from the attachment of one or two more or less complete surfactant bilayers to the initial surfactant monolayer at the air-water interface to the attachment of a greater number of bilayers with a more defective structure. The majority of the wide range of observations of such structures have been made using neutron reflectometry. The possible mechanisms for the attraction of surfactant bilayers to an air-water interface are discussed and particular attention is given to the question of whether these structures are true equilibrium structures. (C) 2019 Elsevier B.V. All rights reserved.

引用

页码：43 / 86

页数：44

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