Temperature dependence of rotational excitation rate coefficients of SH(X2Π) in collision with He

被引：6

作者：

Klos, J. ^{[1
,2
]}

Lique, F. ^{[3
]}

Alexander, M. H. ^{[1
,2
]}

机构：

[1] Univ Maryland, Dept Chem & Biochem, College Pk, MD 20742 USA

[2] Univ Maryland, Inst Phys Sci & Technol, College Pk, MD 20742 USA

[3] Univ Havre, CNRS, LOMC FRE 3102, F-76058 Le Havre, France

来源：

CHEMICAL PHYSICS LETTERS | 2009年 / 476卷 / 4-6期

基金：

美国国家科学基金会;

关键词：

INELASTIC-COLLISIONS; QUANTUM SCATTERING; MOLECULAR CLOUDS; SH; SPECTRUM; COMPLEX; STATES; CO(A;

D O I：

10.1016/j.cplett.2009.04.063

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We report fully-quantum, close-coupling (CC) calculations of inelastic integral cross sections of mercapto radical (SH) collisions with He. Scattering calculations, which take into account the fine-structure of SH, are done on a grid of collision energies large enough to ensure converged state-to-state rate coefficients for temperatures ranging from 1 K up to 350 K. The calculated cross sections and rate coefficients exhibit sizeable, parity-dependent propensities. (C) 2009 Elsevier B. V. All rights reserved.

引用

页码：135 / 137

页数：3

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