New B-substituted derivatives of m-carborane, p-carborane, and cobalt bis(1,2-dicarbollide) anion

被引：37

作者：

Beletskaya, IP

Bregadze, VI ^{[1
]}

Ivushkin, VA

Petrovskii, PV

Sivaev, IB

Sjöberg, S

Zhigareva, GG

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow, Russia

[2] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Moscow 119991, Russia

[3] Uppsala Univ, Dept Chem Organ Chem, Uppsala, Sweden

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2004年 / 689卷 / 18期

基金：

俄罗斯基础研究基金会;

关键词：

m-carborane; p-carborane; cobalt bis(1,2-dicarbollide) anion; cross-coupling reactions; palladium catalysis;

D O I：

10.1016/j.jorganchem.2004.05.047

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The Pd-catalyzed cross-coupling reactions of B-i bond in m- and p-carboranes and cobalt bis(1,2-dicarbollide) anion with organomagnesium and organozinc compounds were studied. Carboranyl derivatives of furan, thiophene, indole, pyridine and quinoline were synthesized. 2-Pyridylethynyl and 3-quinolylethynyl derivatives of p-carborane were prepared by Pd-catalyzed cross-coupling reactions using corresponding alkynes or their magnesium derivatives. (C) 2004 Elsevier B.V. All rights reserved.

引用

收藏

页码：2920 / 2929

页数：10

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