Tris{2-[4-(2-pyridyl)pyrimidin-2-ylsulfanyl]ethyl}amine

被引：2

作者：

Wang, Jian-Quan ^{[1
]}

Zhang, Ya-Wen ^{[1
]}

Cheng, Lin ^{[1
]}

机构：

[1] SE Univ, Sch Chem & Chem Engn, Nanjing 211189, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷

关键词：

LIGANDS;

D O I：

10.1107/S160053680902741X

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The tripodal character of the title compound, C33H30N10S3, arises from the three thioether arms surrounding a central amine N atom. The three arms have approximately the same conformation but distinct geometries in a trans-trans-cis conformation, resulting in a short pyridine-sulfanyl N center dot center dot center dot S distance of 4.320 (7) angstrom. The distances of the central N atom to the N atoms of three pyridine rings in the arms are 8.305 ( 7), 8.032 (7) and 5.076 (9) angstrom. In the crystal, molecules are joined into a three-dimensional supramolecular network via effective pi-pi stacking between adjacent heterocycles [centroid-centroid distances of 3.700 (3)-4.118 (4) angstrom between adjacent interlayer pyrimidine rings and 3.676 (4) angstrom between the pyridine rings].

引用

页码：O1889 / U3239

页数：13

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