Palladium(0) supported on carbon nanotubes as an efficient catalyst of the CC bond hydrogenation

被引：32

作者：

Starodubtseva, Eugenia V. ^{[1
]}

Vinogradov, Maxim G. ^{[1
]}

Turova, Olga V. ^{[1
]}

Bumagin, Nikolai A. ^{[2
]}

Rakov, Eduard G. ^{[3
]}

Sokolov, Viatcheslav I. ^{[4
]}

机构：

[1] Russian Acad Sci, ND Zelinsky Inst Organ Chem, Moscow 119991, Russia

[2] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia

[3] DI Mendeleev Univ Chem Technol Russia, Moscow 125047, Russia

[4] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia

来源：

CATALYSIS COMMUNICATIONS | 2009年 / 10卷 / 10期

关键词：

Palladium; Carbon nanotubes; Catalytic hydrogenation; Acetylenic hydrocarbons; SELECTIVE HYDROGENATION; NANOPARTICLES; PD;

D O I：

10.1016/j.catcom.2009.03.012

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Palladium supported on carbon nanotubes catalyzes efficiently hydrogenation of the C C bond of tolane, phenylacetylene and 1-heptyne to give a mixture of intermediate ethylenic and completely reduced hydrocarbons. The composition of hydrogenation products depends greatly on the structure of the starting reagent and reaction conditions. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：1441 / 1442

页数：2

共 11 条

[1] Catalytic activity of palladium supported on single wall carbon nanotubes compared to palladium supported on activated carbon Study of the Heck and Suzuki couplings, aerobic alcohol oxidation and selective hydrogenation [J].

Corma, A ;

Garcia, H ;

Leyva, A .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2005, 230 (1-2) :97-105

[2]

Rakov EG, 2004, RUSS J PHYS CHEM+, V78, P1966

[3] Fullerene complexes with palladium and rhodium as catalysts for acetylenic bond hydrogenation [J].

Starodubtseva, Eugenia V. ;

Sokolov, Viatcheslav I. ;

Bashilov, Vasily V. ;

Novikov, Yurii N. ;

Martynova, Ekaterina V. ;

Vinogradov, Maxim G. ;

Turova, Olga V. .

MENDELEEV COMMUNICATIONS, 2008, 18 (04) :209-210

[4] Pd nanoparticles introduced inside multi-walled carbon nanotubes for selective hydrogenation of cinnamaldehyde into hydrocinnamaldehyde [J].

Tessonnier, JP ;

Pesant, L ;

Ehret, G ;

Ledoux, MJ ;

Pham-Huu, C .

APPLIED CATALYSIS A-GENERAL, 2005, 288 (1-2) :203-210

[5]

Tessonnier JP, 2002, STUD SURF SCI CATAL, V143, P697

[6] The synthesis of structured Pd/C hydrogenation catalysts by the chemical vapor deposition of Pd(ally1)Cp onto functionalized carbon nanotubes anchored to vapor grown carbon microfibers [J].

Xia, W ;

Schlüter, OFK ;

Liang, CH ;

van den Berg, MWE ;

Guraya, M ;

Muhler, M .

CATALYSIS TODAY, 2005, 102 :34-39

[7]

YANOWSKA I, 2007, J MOL CATAL A-CHEM, V267, P92

[8] Supercritical fluid synthesis and characterization of catalytic metal nanoparticles on carbon nanotubes [J].

Ye, XR ;

Lin, YH ;

Wang, CM ;

Engelhard, MH ;

Wang, Y ;

Wai, CM .

JOURNAL OF MATERIALS CHEMISTRY, 2004, 14 (05) :908-913

[9] Decorating catalytic palladium nanoparticles on carbon nanotubes in supercritical carbon dioxide [J].

Ye, XR ;

Lin, YH ;

Wai, CM .

CHEMICAL COMMUNICATIONS, 2003, (05) :642-643

[10] Microemulsion-templated synthesis of carbon nanotube-supported Pd and Rh nanoparticles for catalytic applications [J].

Yoon, B ;

Wai, CM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (49) :17174-17175

← 1 2 →