Mechanochemical Preparation of a MoS2/Polyaniline Nanocomposite with High Electrochemical Capacity

被引：4

作者：

Kozarenko, O. A. ^{[1
]}

Khazieieva, O. A. ^{[1
]}

Dyadyun, V. S. ^{[1
]}

Posudievsky, O. Yu. ^{[1
]}

Koshechko, V. G. ^{[1
]}

Pokhodenko, V. D. ^{[1
]}

机构：

[1] Natl Acad Sci Ukraine, LV Pisarzhevsky Phys Chem Inst, UA-03028 Kiev, Ukraine

来源：

THEORETICAL AND EXPERIMENTAL CHEMISTRY | 2015年 / 51卷 / 05期

关键词：

nanocomposite; lithium battery; mechanochemistry; molybdenum disulfide; polyaniline; LITHIUM ION BATTERIES; RECHARGEABLE BATTERIES; LIQUID EXFOLIATION; CATHODE MATERIAL; METAL ANODE; MOS2; PERFORMANCE; POLYMERS; STORAGE; NANOSHEETS;

D O I：

10.1007/s11237-015-9428-4

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A hybrid polyaniline nanocomposite derived from polyaniline in the emeraldine base state and nanostructurized MoS (2) was prepared by a mechanochemical method. The electrochemical properties of the MoS2/PAni nanocomposite as the active component of a lithium battery cathode were studied. This material has a high specific capacity of similar to 270 A center dot h/kg, which is due to the significantly greater specific capacities of the organic and inorganic components relative to their characteristics in the individual states. This enhancement may be attributed to the effects of the nanocomposite components on the electrochemical behavior of each other.

引用

页码：293 / 300

页数：8

共 27 条

[1]

Beqqali O.E., 1997, SYNTHETIC MET, V90, P165, DOI DOI 10.1016/S0379-6779(98)80002-7

[2] Two-Dimensional Nanosheets Produced by Liquid Exfoliation of Layered Materials [J].

Coleman, Jonathan N. ;

Lotya, Mustafa ;

O'Neill, Arlene ;

Bergin, Shane D. ;

King, Paul J. ;

Khan, Umar ;

Young, Karen ;

Gaucher, Alexandre ;

De, Sukanta ;

Smith, Ronan J. ;

Shvets, Igor V. ;

Arora, Sunil K. ;

Stanton, George ;

Kim, Hye-Young ;

Lee, Kangho ;

Kim, Gyu Tae ;

Duesberg, Georg S. ;

Hallam, Toby ;

Boland, John J. ;

Wang, Jing Jing ;

Donegan, John F. ;

Grunlan, Jaime C. ;

Moriarty, Gregory ;

Shmeliov, Aleksey ;

Nicholls, Rebecca J. ;

Perkins, James M. ;

Grieveson, Eleanor M. ;

Theuwissen, Koenraad ;

McComb, David W. ;

Nellist, Peter D. ;

Nicolosi, Valeria .

SCIENCE, 2011, 331 (6017) :568-571

[3] Facile synthesis of hierarchical MoS2 microspheres composed of few-layered nanosheets and their lithium storage properties [J].

Ding, Shujiang ;

Zhang, Dongyang ;

Chen, Jun Song ;

Lou, Xiong Wen .

NANOSCALE, 2012, 4 (01) :95-98

[4] Superior stability and high capacity of restacked molybdenum disulfide as anode material for lithium ion batteries [J].

Du, Guodong ;

Guo, Zaiping ;

Wang, Shiquan ;

Zeng, Rong ;

Chen, Zhixin ;

Liu, Huakun .

CHEMICAL COMMUNICATIONS, 2010, 46 (07) :1106-1108

[5] Lithium storage in commercial MoS2 in different potential ranges [J].

Fang, Xiangpeng ;

Hua, Chunxiu ;

Guo, Xianwei ;

Hu, Yongsheng ;

Wang, Zhaoxiang ;

Gao, Xueping ;

Wu, Feng ;

Wang, Jiazhao ;

Chen, Liquan .

ELECTROCHIMICA ACTA, 2012, 81 :155-160

[6] Performance of polyaniline/multi-walled carbon nanotubes composites as cathode for rechargeable lithium batteries [J].

He, Ben-Lin ;

Dong, Bin ;

Wang, Wei ;

Li, Hu-Lin .

MATERIALS CHEMISTRY AND PHYSICS, 2009, 114 (01) :371-375

[7]

Julien C., 1994, SOLID STATE BATTERIE

[8] Batteries and charge storage devices based on electronically conducting polymers [J].

Katz, Howard E. ;

Searson, Peter C. ;

Poehler, Theodore O. .

JOURNAL OF MATERIALS RESEARCH, 2010, 25 (08) :1561-1574

[9] Effect of potential range on electrochemical performance of polyaniline as a component of lithium battery electrodes [J].

Kozarenko, Olga A. ;

Dyadyun, Vyacheslav S. ;

Papakin, Mykhailo S. ;

Posudievsky, Oleg Yu ;

Koshechko, Vyacheslav G. ;

Pokhodenko, Vitaly D. .

ELECTROCHIMICA ACTA, 2015, 184 :111-116

[10] A graphene-like MoS2/graphene nanocomposite as a highperformance anode for lithium ion batteries [J].

Liu, Yongchang ;

Zhao, Yanping ;

Jiao, Lifang ;

Chen, Jun .

JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (32) :13109-13115

← 1 2 3 →