Synthesis of blue-violet light wavelength metal (II)-azo complexes and their absorption and thermal properties

被引:23
作者
Huang, FX
Wu, YQ
Gu, DH
Gan, FX
机构
[1] Chinese Acad Sci, Shanghai Inst Opt & Fine Mech, Shanghai 201800, Peoples R China
[2] Heilongjiang Univ, Lab Funct Mat, Haerbin 150080, Peoples R China
关键词
metal (II)-azo complex; synthesis; absorption spectra; thermal stability;
D O I
10.1016/j.matlet.2004.03.007
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Some kinds of metal (II)-azo complexes with blue-violet light wavelength absorption were synthesized using a diazo component, a coupling component and different metal ions (Cu2+, Ni2+ and Zn2+). Their structures were confirmed by elemental analysis, spectral and magnetic data. The solubility of metal (II)-azo complexes in 2, 2, 3, 3-tetrafluoro-1-propanol (TFP) and absorption properties of their films in the region 300-800 nm were measured. The influence on the difference of absorption maximum from metal (II)-azo complexes to azo ligand by different metal ions was studied. In addition, the thermal stability of metal (II)-azo complexes was also reported. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:2461 / 2465
页数:5
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