Effect of gold nanoparticles on the photocatalytic efficiency of ZnO films

被引:29
作者
Georgiev, Peter [1 ]
Kaneva, Nina [2 ]
Bojinova, Assya [2 ]
Papazova, Karolina [2 ]
Mircheva, Kristina [1 ]
Balashev, Konstantin [1 ]
机构
[1] Univ Sofia, Fac Chem & Pharm, Dept Phys Chem, Sofia 1164, Bulgaria
[2] Univ Sofia, Fac Chem & Pharm, Dept Gen & Inorgan Chem, Lab Nanoparticle Sci & Technol, Sofia 1164, Bulgaria
关键词
Gold nanoparticles; Zinc oxide; Thin films; Photocatalysis; Malachite green; AZO-DYE; AU-ZNO; TIO2; PLATINUM; CARBON; ENHANCEMENT; DEGRADATION; OXIDATION; SIZE; UV;
D O I
10.1016/j.colsurfa.2014.02.004
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This study presents a simple and inexpensive method for preparation of ZnO/Au thin film photocatalysts. Nanostructured ZnO and modified with gold nanoparticles zinc oxide films are obtained on glass substrate by dip-coating technique. The precursor suspension is prepared using commercial ZnO powder, ethanol and polyethyleneglycol, while the gold nanoparticles are obtained by classical citrate synthesis. Thin ZnO and ZnO/Au films are characterized by Atomic Force Microscopy (AFM), Scanning Electron Microscopy(SEM), Energy Dispersive X-ray Spectroscopy (EDS), X-ray diffraction and UV-Vis spectroscopy. The photocatalytic action of the samples is studied in respect to Malachite Green photodegradation under UV and visible light irradiation. The modified ZnO/Au films manifest higher photocatalytic efficiency under UV and visible light illumination in comparison to ZnO ones. A possible mechanism for explanation of the observed effect is proposed. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:240 / 247
页数:8
相关论文
共 39 条
  • [11] The influence of platinum on UV and 'visible' photocatalysis by rutile and Degussa P25
    Egerton, Terry A.
    Mattinson, John A.
    [J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2008, 194 (2-3) : 283 - 289
  • [12] Cobalt-doped ZnO - a room temperature dilute magnetic semiconductor
    Fitzgerald, CB
    Venkatesan, M
    Lunney, JG
    Dorneles, LS
    Coey, JMD
    [J]. APPLIED SURFACE SCIENCE, 2005, 247 (1-4) : 493 - 496
  • [13] A highly efficient Ag-ZnO photocatalyst: Synthesis, properties, and mechanism
    Georgekutty, Reenamole
    Seery, Michael K.
    Pillai, Suresh C.
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (35) : 13563 - 13570
  • [14] Implementing atomic force microscopy (AFM) for studying kinetics of gold nanoparticle's growth
    Georgiev, Peter
    Bojinova, Assya
    Kostova, Bistra
    Momekova, Denitsa
    Bjornholm, Thomas
    Balashev, Konstantin
    [J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2013, 434 : 154 - 163
  • [15] Synthesis, characterization, and visible light activity of new nanoparticle photocatalysts based on silver, carbon, and sulfur-doped TiO2
    Hamal, Dambar B.
    Klabunde, Kenneth J.
    [J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2007, 311 (02) : 514 - 522
  • [16] Enhancement of the photocatalytic activity of various TiO2 materials by platinisation
    Hufschmidt, D
    Bahemann, D
    Testa, JJ
    Emilio, CA
    Litter, MI
    [J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2002, 148 (1-3) : 223 - 231
  • [17] Influence of the size of gold nanoparticles deposited on TiO2 upon the photocatalytic destruction of oxalic acid
    Iliev, V.
    Tomova, D.
    Bilyarska, L.
    Tyuliev, G.
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2007, 263 (1-2) : 32 - 38
  • [18] Enhancement of photocatalytic oxidation of oxalic acid by gold modified WO3/TiO2 photocatalysts under UV and visible light irradiation
    Iliev, V.
    Tomova, D.
    Rakovsky, S.
    Eliyas, A.
    Puma, G. Li
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2010, 327 (1-2) : 51 - 57
  • [19] Kim KS, 2013, J COMMUN NETW-S KOR, V15, P1, DOI [10.1109/JCN.2013.000003, 10.12812/ksms.2013.15.2.1]
  • [20] Visible light active platinum-ion-doped TiO2 photocatalyst
    Kim, S
    Hwang, SJ
    Choi, WY
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (51) : 24260 - 24267