Synthesis and reactivity of propionitrilium derivatives of cobalt and iron bis(dicarbollides)

被引：14

作者：

Bogdanova, Ekaterina, V ^{[1
,2
]}

Stogniy, Marina Yu ^{[1
,2
]}

Chekulaeva, Lyubov A. ^{[1
]}

Anisimov, Aleksei A. ^{[1
,3
]}

Suponitsky, Kyrill Yu ^{[1
,4
]}

Sivaev, Igor B. ^{[1
,5
]}

Grin, Mikhail A. ^{[2
]}

Mironov, Andrey F. ^{[2
]}

Bregadze, Vladimir, I ^{[1
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, 28 Vavilov Str, Moscow 119991, Russia

[2] MIREA Russian Technol Univ, MV Lomonosov Inst Fine Chem Technol, 86 Vernadsky Av, Moscow 119571, Russia

[3] DI Mendeleev Russian Chem Technol Univ, 9 Miusskaya Sq, Moscow 125047, Russia

[4] Russian Acad Sci, NS Kurnakov Inst Gen & Inorgan Chem, 31 Leninskii Av, Moscow 119991, Russia

[5] GV Plekhanov Russian Univ Econ, 36 Stremyannyi Line, Moscow 117997, Russia

来源：

NEW JOURNAL OF CHEMISTRY | 2020年 / 44卷 / 37期

基金：

俄罗斯基础研究基金会;

关键词：

EXTRACTION UNEX PROCESS; CLOSO-DECABORATE ANION; RADICAL-CATION SALTS; NUCLEOPHILIC-ADDITION; SUBSTITUTED DERIVATIVES; TRANSITION-METALS; CRYSTAL-STRUCTURE; BORON; SEPARATION; ACTINIDES;

D O I：

10.1039/d0nj03017a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of propionitrilium derivatives of cobalt and iron bis(dicarbollides) [8-EtC N-3,3 '-M(1,2-C2B9H10)(1',2'-C2B9H11)] (M = Co, Fe) by the reaction of the cesium salts of the parent bis(dicarbollide) anions [3,3'-M(1,2-C2B9H11)(2)](-) with propionitrile in the presence oftert-butyl bromide is described. The nucleophilic addition reactions of water, alcohols, and thiols with the -N+=C triple bond of the prepared nitrilium derivatives were studied and the corresponding iminols [8-EtC(OH) HN-3,3'-M(1,2-C2B9H10)(1',2'-C2B9H11)] (M = Co, Fe), imidates [8-EtC(OR) HN-3,3 '-M(1,2-C2B9H10)(1',2'-C2B9H11)] (M = Co, R = Me, Et, i-Pr, Bu; M = Fe, R = Et), and thioimidates [8-EtC(SR) HN-3,3'-Co(1,2-C2B9H10)(1',2'-C2B9H11)] (R = Et, Bu, Hx) were synthesized as mixtures ofEandZ-isomers, some of which could be separated by the column chromatography on silica. The molecular structure of [(Z)-8-EtC(OiPr) HN-3,3'-Co(1,2-C2B9H10)(1',2'-C2B9H11)] was determined by single-crystal X-ray diffraction study.

引用

页码：15836 / 15848

页数：13

共 86 条

[1]

[Anonymous], 1965, J CHEM SOC CHEM COMM

[2]

[Anonymous], 2004, Gaussian03

[3]

[Anonymous], 2014, APEX2 SAINT

[4] Synthesis and structure of bis(methylsulfanyl) derivatives of iron bis(dicarbollide) [J].

Anufriev, Sergey A. ;

Erokhina, Svetlana A. ;

Suponitsky, Kyrill Yu. ;

Anisimov, Aleksei A. ;

Laskova, Julia N. ;

Godovikov, Ivan A. ;

de Biani, Fabrizia Fabrizi ;

Corsini, Maddalena ;

Sivaev, Igor B. ;

Bregadze, Vladimir I. .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2018, 865 :239-246

[5] Methylsulfanyl-Stabilized Rotamers of Cobalt Bis(dicarbollide) [J].

Anufriev, Sergey A. ;

Erokhina, Svetlana A. ;

Suponitsky, Kyrill Yu. ;

Godovikov, Ivan A. ;

Filippov, Oleg A. ;

de Biani, Fabrizia Fabrizi ;

Corsini, Maddalena ;

Chizhov, Alexander O. ;

Sivaev, Igor B. .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2017, (38-39) :4444-4451

[6] Synthesis of 10-Methylsulfide and 10-Alkylmethylsulfonium nido-Carborane Derivatives: B-H•••π Interactions between the B-H-B Hydrogen Atom and Alkyne Group in 10-RC≡CCH2S(Me)-7,8-C2B9H11 [J].

Anufriev, Sergey A. ;

Sivaev, Igor B. ;

Suponitsky, Kyrill Yu. ;

Godovikov, Ivan A. ;

Bregadze, Vladimir I. .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2017, (38-39) :4436-4443

[7]

Armarego WLF, 2009, PURIFICATION OF LABORATORY CHEMICALS, 6TH EDITION, P1

[8] ATOMS IN MOLECULES [J].

BADER, RFW .

ACCOUNTS OF CHEMICAL RESEARCH, 1985, 18 (01) :9-15

[9] New B-substituted derivatives of m-carborane, p-carborane, and cobalt bis(1,2-dicarbollide) anion [J].

Beletskaya, IP ;

Bregadze, VI ;

Ivushkin, VA ;

Petrovskii, PV ;

Sivaev, IB ;

Sjöberg, S ;

Zhigareva, GG .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2004, 689 (18) :2920-2929

[10]

Bokach N.A., 2005, RUSS CHEM REV+, V74, P153, DOI DOI 10.1070/RC2005V074N02ABEH000979

← 1 2 3 4 5 6 7 8 9 →