Ti 2p and O 1s core levels and chemical bonding in titanium-bearing oxides

被引：296
作者：
Atuchin, Victor V. [1 ]
Kesler, Valery G.
Pervukhina, Natalia V.
Zhang, Zhaoming
机构：
[1] Russian Acad Sci, Inst Semicond Phys, SB, Lab Opt Mat & Struct, Novosibirsk 630090, Russia
[2] Russian Acad Sci, Inst Semicond Phys, SB, Ctr Tech, Novosibirsk 630090, Russia
[3] Russian Acad Sci, Inst Inorgan Chem, SB, Lab Crystal Chem, Novosibirsk 630090, Russia
[4] Australian Nucl Sci & Technol Org, Menai, NSW 2234, Australia
来源：
JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA | 2006年 / 152卷 / 1-2期
关键词：
titanates; chemical bonding; XPS;
D O I：
10.1016/j.elspec.2006.02.004
中图分类号：
O433 [光谱学];
学科分类号：
0703 ; 070302 ;
摘要：
A set of available experimental data on the binding energies of Ti 2p(3/2) and 0 Is core levels in titanium-bearing oxides has been presented by using the binding energy difference (0 1s-Ti 2P(3/2)) as a robust parameter to characterize these compounds. An empirical relationship between the (0 1s-Ti 2P(3/2)) values measured with XPS and the mean chemical bond length L(Ti-O) in these crystals has been discussed for Ti4+-compounds. (c) 2006 Elsevier B.V. All rights reserved.
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页码：18 / 24
页数：7
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