Nanocomposites of carbon allotropes with TiO2 as effective photoanodes for efficient dye-sensitized solar cells

被引:16
作者
Mehmood, Umer [1 ,2 ]
Khan, Anwar Ul Haq [1 ]
Qaiser, Asif Ali [1 ]
Bashir, Sheraz [3 ]
Younas, Muhammad [4 ]
机构
[1] Univ Engn & Technol Lahore, Dept Polymer & Proc Engn, Lahore, Pakistan
[2] KFUPM, Ctr Res Excellence Renewable Energy, Dhahran, Saudi Arabia
[3] Univ Hafr Albatin, Dept Chem Engn, Hafar Al Batin, Saudi Arabia
[4] KFUPM, Dept Phys, P0B 5050, Dhahran 31261, Saudi Arabia
关键词
Carbon; DSSC; PERFORMANCE; NANOTUBES;
D O I
10.1016/j.matlet.2018.05.127
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this work, nanocomposites of carbon allotropes with TiO2 have been used as photoanodes to improve the photovoltaic performance of dye-sensitized solar cells (DSSCs). Multi-walled carbon nanotubes and graphene materials have been mixed with TiO2 paste to form nanocomposites. Transmission Electron Microscopy (TEM) has been used to confirm the dispersion of MWCNTs and graphene materials in TiO2. The electrochemical impedance spectroscopic, current-voltage characteristics and incident photon-to-current efficiency have been carried to characterize DSSCs. Results demonstrate that nanocomposite photoanodes enhance the power-conversion-efficiency of DSSCs. However, results also show that graphene/TiO2 based DSSC exhibits PCE of 5.25%, which is about 14% higher than MWCNTs/TiO2 based solar cell (4.20%). (C) 2018 Elsevier B.V. All rights reserved.
引用
收藏
页码:125 / 128
页数:4
相关论文
共 15 条
[1]   Incorporation of multiwalled carbon nanotubes into TiO2 nanowires for enhancing photovoltaic performance of dye-sensitized solar cells via highly efficient electron transfer [J].
Ahn, Ji Young ;
Kim, Ji Hoon ;
Moon, Kook Joo ;
Kim, Jong Hyun ;
Lee, Chang Sun ;
Kim, Min Young ;
Kang, Jae Wook ;
Kim, Soo Hyung .
SOLAR ENERGY, 2013, 92 :41-46
[2]   Ultrahigh electron mobility in suspended graphene [J].
Bolotin, K. I. ;
Sikes, K. J. ;
Jiang, Z. ;
Klima, M. ;
Fudenberg, G. ;
Hone, J. ;
Kim, P. ;
Stormer, H. L. .
SOLID STATE COMMUNICATIONS, 2008, 146 (9-10) :351-355
[3]   Hybrid Carbon Nanotubes-TiO2 Photoanodes for High Efficiency Dye-Sensitized Solar Cells [J].
Dembele, Kadiatou Therese ;
Selopal, Gurpreet Singh ;
Soldano, Caterina ;
Nechache, Riad ;
Cesar Rimada, Julio ;
Concina, Isabella ;
Sberveglieri, Giorgio ;
Rosei, Federico ;
Vomiero, Alberto .
JOURNAL OF PHYSICAL CHEMISTRY C, 2013, 117 (28) :14510-14517
[4]   Nanostructure control of graphene-composited TiO2 by a one-step solvothermal approach for high performance dye-sensitized solar cells [J].
He, Ziming ;
Guai, Guanhong ;
Liu, Jing ;
Guo, Chunxian ;
Loo, Joachim Say Chye ;
Li, Chang Ming ;
Tan, Timothy Thatt Yang .
NANOSCALE, 2011, 3 (11) :4613-4616
[5]   Incorporation of functionalized single-wall carbon nanotubes in dye-sensitized TiO2 solar cells [J].
Jang, SR ;
Vittal, R ;
Kim, KJ .
LANGMUIR, 2004, 20 (22) :9807-9810
[6]   Electron storage in single wall carbon nanotubes. Fermi level equilibration in semiconductor-SWCNT suspensions [J].
Kongkanand, Anusorn ;
Kamat, Prashant V. .
ACS NANO, 2007, 1 (01) :13-21
[7]   Preparation and performance of dye-sensitized solar cells based on ZnO-modified TiO2 electrodes [J].
Li, Sheng-jun ;
Lin, Yuan ;
Tan, Wei-wei ;
Zhang, Jing-bo ;
Zhou, Xiao-wen ;
Chen, Jin-mao ;
Chen, Zeng .
INTERNATIONAL JOURNAL OF MINERALS METALLURGY AND MATERIALS, 2010, 17 (01) :92-97
[8]   Enhanced Conversion Efficiency in Dye-Sensitized Solar Cells Based on Hydrothermally Synthesized TiO2-MWCNT Nanocomposites [J].
Muduli, Subas ;
Lee, Wonjoo ;
Dhas, Vivek ;
Mujawar, Sarfraj ;
Dubey, Megha ;
Vijayamohanan, K. ;
Han, Sung-Hwan ;
Ogale, Satishchandra .
ACS APPLIED MATERIALS & INTERFACES, 2009, 1 (09) :2030-2035
[9]   Optimizing dyes for dye-sensitized solar cells [J].
Robertson, N .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (15) :2338-2345
[10]   Graphene-Based Ultracapacitors [J].
Stoller, Meryl D. ;
Park, Sungjin ;
Zhu, Yanwu ;
An, Jinho ;
Ruoff, Rodney S. .
NANO LETTERS, 2008, 8 (10) :3498-3502