Customized, core-modified corroles from [2+2] condensation of dipyrromethanes

被引：29

作者：

Cho, WS ^{[1
]}

Lee, CH ^{[1
]}

机构：

[1] Kangweon Natl Univ, Dept Chem, Chunchon 200701, South Korea

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 05期

关键词：

corrole; dipyrromethanes; 2+2] condensation;

D O I：

10.1016/S0040-4039(99)02142-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Corroles and core-modified corroles were synthesized by acid-catalyzed condensation under low-scrambling conditions. The synthesis utilized [2+2] condensation of two different dipyrromethanes. The condensation afforded different corroles bearing heteroatoms in a predesignated location depending on the starting dipyrromethanes. Selective alpha-alpha' linkage was achieved by positioning a linking carbon unit at a different site of dipyrromethanes. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：697 / 701

页数：5

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