Assembly of a new inorganic-organic frameworks based on [Sb4Mo12(OH)6O48]10- Polyanion

被引：7

作者：

Thabet, Safa ^{[1
]}

Ayed, Meriem ^{[1
]}

Ayed, Brahim ^{[1
]}

Haddad, Amor ^{[1
]}

机构：

[1] Inst Super Sci Appliquees & Technol, Lab Mat & Cristallochim, Mahdia 5111, Tunisia

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2014年 / 1075卷

关键词：

Organic-inorganic hybrid; Polyoxometalates; Molybdoantimonate; 2-Methylimidazole; Electrochemical behavior; SB-III; CRYSTAL-STRUCTURE; AS-III; TE-IV; SE-IV; STRUCTURAL-CHARACTERIZATION; POLYOXOMETALATE CLUSTERS; MOLECULAR SYMMETRY; BETA-OCTAMOLYBDATE; BUILDING-BLOCKS;

D O I：

10.1016/j.molstruc.2014.06.043

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new organic-inorganic hybrid material, (C4N2H7)(8)[K(H2O)](2)[Sb4Mo12(OH)(6)O-48]center dot 16H(2)O (1) has been isolated by the conventional solution method and characterized by elemental analysis, single-crystal X-ray diffraction, infrared spectroscopy, UV-visible spectroscopies, cyclic voltammetry and TG-DTA analysis. The compound crystallizes in the triclinic space group P - 1 with a = 13.407(6) angstrom, b = 13.906(2) angstrom, c = 14.657(7) angstrom, alpha = 77.216(9)degrees, beta = 71.284(6)degrees, gamma = 71.312(3)degrees and Z=1. The crystal structure exhibits an infinite 1D inorganic structure built from [Sb4Mo12(OH)(6)O-48](10-) clusters and potassium cations; adjacent chains are further joined up hydrogen bonding interactions between protonated 2-methylimidazolim cations, water molecules and polyoxoanions to form a 3D supramolecular architecture. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：26 / 31

页数：6

共 47 条

[1] Controllable growth of chains and grids from polyoxomolybdate building blocks linked by silver(I) dimers [J].

Abbas, H ;

Pickering, AL ;

Long, DL ;

Kögerler, P ;

Cronin, L .

CHEMISTRY-A EUROPEAN JOURNAL, 2005, 11 (04) :1071-1078

[2] Density functional theory and Hartree-Fock studies:: Geometry, vibrational frequencies and electronic properties of Anderson-type heteropolyanion, [XM6O24]n- (X = TeVI, IVII and M = Mo, W) and [SbVW6O24]7- [J].

Alizadeh, M. H. ;

Salimi, A. R. .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2006, 65 (05) :1104-1111

[3] A HETEROPOLYANION WITH FIVEFOLD MOLECULAR SYMMETRY THAT CONTAINS A NONLABILE ENCAPSULATED SODIUM-ION - THE STRUCTURE AND CHEMISTRY OF [NAP5W30O110]14- [J].

ALIZADEH, MH ;

HARMALKER, SP ;

JEANNIN, Y ;

MARTINFRERE, J ;

POPE, MT .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (09) :2662-2669

[4] Novel catalytic acetylation of alcohols with Preyssler's anion, [NaP5Wa30O110]14- [J].

Alizadeh, MH ;

Razavi, H ;

Bamoharram, FF ;

Hassanzadeh, MK ;

Khoshnavazi, R ;

Zonoz, FM .

KINETICS AND CATALYSIS, 2003, 44 (04) :524-528

[5] A pillar-layered three-dimensional open framework constructed from polyoxometalate-supported metal coordination complex layers and bi-supporting polyoxometalate clusters [J].

An, Haiyan ;

Xu, Tieqi ;

Wang, Enbo ;

Meng, Changgong .

INORGANIC CHEMISTRY COMMUNICATIONS, 2007, 10 (12) :1453-1456

[6] Self-assembly of a series of extended architectures based on polyoxometalate clusters and silver coordination complexes [J].

An, HY ;

Li, YG ;

Wang, EB ;

Xiao, DR ;

Sun, CY ;

Xu, L .

INORGANIC CHEMISTRY, 2005, 44 (17) :6062-6070

[7] A series of new polyoxoanion-based inorganic-organic hybrids:: (C6NO2H5)[(H2O)4(C6NO2H5)Ln(CrMo6H6O24)]•4H2O (Ln = Ce, Pr, La and Nd) with a chiral layer structure [J].

An, HY ;

Xiao, DR ;

Wang, EB ;

Li, YG ;

Xu, L .

NEW JOURNAL OF CHEMISTRY, 2005, 29 (05) :667-672

[8] First structurally characterized palladium(II)-substituted polyoxoanion:: [Cs2Na(H2O)10Pd3(α-SbIIIW9O33)2]9- [J].

Bi, LH ;

Reicke, M ;

Kortz, U ;

Keita, B ;

Nadjo, L ;

Clark, RJ .

INORGANIC CHEMISTRY, 2004, 43 (13) :3915-3920

[9] BOND-VALENCE PARAMETERS OBTAINED FROM A SYSTEMATIC ANALYSIS OF THE INORGANIC CRYSTAL-STRUCTURE DATABASE [J].

BROWN, ID ;

ALTERMATT, D .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1985, 41 (AUG) :244-247

[10] Improved catalytic performance of Keggin-type polyoxometalates in the oxidation of isobutane to methacrylic acid under hydrocarbon-lean conditions using antimony-doped catalysts [J].

Cavani, F ;

Mezzogori, R ;

Pigamo, A ;

Trifirò, F .

CHEMICAL ENGINEERING JOURNAL, 2001, 82 (1-3) :33-42

← 1 2 3 4 5 →