Polystyrene assisted superhydrophobic silica coatings with surface protection and self-cleaning approach

被引:97
作者
Pawar, Popat G. [2 ]
Xing, Ruimin [1 ]
Kambale, Rahul C. [3 ]
Kumar, A. Madhan [4 ]
Liu, Shanhu [1 ]
Latthe, Sanjay S. [5 ]
机构
[1] Henan Univ, Coll Chem & Chem Engn, Inst Mol & Crystal Engn, Henan Key Lab Polyoxometalate Chem, Kaifeng, Peoples R China
[2] Shivaji Polytech Coll, Sangola 413307, MH, India
[3] Savitribai Phule Pune Univ, Dept Phys, Pune, Maharashtra, India
[4] King Fahd Univ Petr & Minerals, Res Inst, Ctr Res Excellence Corros, Dhahran, Saudi Arabia
[5] Raje Ramrao Mahavidyalaya, Dept Phys, Self Cleaning Res Lab, Jath 416404, Maharashtra, India
关键词
Superhydrophobic; Contact angle; Self-cleaning; Corrosion; Sol-gel; Wetting; CORROSION PROTECTION; NANOCOMPOSITE; STATE; NANOPARTICLES; ALUMINUM; FILMS;
D O I
10.1016/j.porgcoat.2017.01.016
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Both surface morphology and surface energy of solid surface conclude its wettability, either in Wenzel's hydrophobic or Cassie-Baxter's superhydrophobic wetting state. The superhydrophobic silica coatings were prepared by spin deposition technique from a mixture of hydrophobically modified silica particles and polystyrene. To enhance the adherency of the coating on the substrate and also to improve the durability of the coating, polymer is especially utilized in the coating solution. The durability of the superhydrophobic coating was confirmed by resistency towards water jet impact. The consequence of number of spin deposited layers on the wettability of the coatings was precisely studied. The static and dynamic water contact angle of 158 and 9 were achieved on the coating surface. Freely rolling spherical Water drops on the non-wettable solid surface are favourable for the self-cleaning effect and so the prepared superhydrophobic coatings revealed superior self-cleaning performance. An anti-corrosion performance of the superhydrophobic coating was also confirmed using electrochemical corrosion experiments in 3.5% NaCI solution with long immersion time. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:235 / 244
页数:10
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