Thermodynamic characteristics of the adsorption of 1,3,4-oxadiazoles and 1,2,4,5-tetrazines from methanol and water-methanol solutions onto hypercrosslinked polystyrene

被引:3
作者
Saifutdinov, B. R. [1 ]
Davankov, V. A. [2 ]
Il'in, M. M. [2 ]
机构
[1] Samara State Tech Univ, Samara 443100, Russia
[2] Russian Acad Sci, Nesmeyanov Inst Organoelement Cpds, Moscow 119334, Russia
基金
俄罗斯基础研究基金会;
关键词
hypercrosslinked polystyrene; thermodynamic characteristics; high performance liquid chromatography; ULTIMATE DEGREES; CROSS-LINKING; NETWORKS; SORPTION;
D O I
10.1134/S0036024417030244
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The thermodynamic characteristics of the adsorption of several 1,3,4-oxadiazoles and 1,2,4,5- tetrazines from methanol and water-methanol solutions onto neutral hypercrosslinked polystyrene with a degree of crosslinking of 150% are determined via high performance liquid chromatography. It is shown how the obtained characteristics depend on the molecular structure of adsorbed substances and the composition of the liquid phase in which adsorption occurs.
引用
收藏
页码:577 / 580
页数:4
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