A simple acetylation of alcohols using ZnO nanopowder synthesized by microwave irradiation

被引:0
作者
Javaherian, Mohammad [1 ]
Sabzi, Hashem Eskandari [2 ]
机构
[1] Shahid Chamran Univ Ahvaz, Coll Sci, Dept Chem, Ahvaz, Iran
[2] Islamic Azad Univ, Sci & Res Branch, Dept Chem, Khouzestan, Iran
来源
INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY | 2014年 / 53卷 / 05期
关键词
ZnO nanopowder; acetylation; alcohol; acetic acid; CATALYZED ACETYLATION; HIGHLY EFFICIENT; POWERFUL CATALYST; REUSABLE CATALYST; ACETIC-ANHYDRIDE; LEWIS-ACID; ACYLATION; PHENOLS; AMINES; THIOLS;
D O I
暂无
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
An efficient and selective method for acetylation of alcohols using ZnO nanopowder is described. In this method, alcohols are refluxed with a mixture of CH3COOH in the presence of catalytic amounts of ZnO nanopowder to afford their corresponding esters in good yields. This methodology is highly efficient for various structurally different alcohols: 1 degrees, 2 degrees, 3 degrees. The prepared nano zinc oxide used in acetylation of alcohols which in comparison to ordinary ZnO has apparent advantages in promoting the yields of product formation.
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页码:631 / 634
页数:4
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