Self-Assembled Hexadecanitroxide

被引：6

作者：

Neviani, Paolo ^{[1
]}

Mileo, Elisabetta ^{[1
]}

Masiero, Stefano ^{[1
]}

Pieraccini, Silvia ^{[1
]}

Lucarini, Marco ^{[1
]}

Spada, Gian Piero ^{[1
]}

机构：

[1] Alma Mater Studiorum Univ Bologna, Dipartimento Chim Organ A Mangini, I-40126 Bologna, Italy

来源：

ORGANIC LETTERS | 2009年 / 11卷 / 14期

关键词：

GUANOSINE DERIVATIVES; CIRCULAR-DICHROISM; QUARTET FORMATION; CATION; QUADRUPLEX; SPECTROSCOPY; SCAFFOLDS; BINDING; BONDS;

D O I：

10.1021/ol901028h

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A radical-armed guanosine derivative shows drastic magnetic changes by addition (removal) of alkali metal cations corresponding to the reversible assembly (disassembly). In the presence of templating metal ions, the assembly is formed by 8 molecules and 16 open-shell moieties confined in a sphere with a diameter of ca. 30 angstrom.

引用

页码：3004 / 3007

页数：4

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