Catalytic transfer hydrogenation of furfural into furfuryl alcohol over Ni-Fe-layered double hydroxide catalysts

被引：13

作者：

Wang, Tao ^{[1
]}

Hu, Aiyun ^{[1
]}

Wang, Haijun ^{[1
]}

Xia, Yongmei ^{[2
]}

机构：

[1] Jiangnan Univ, Sch Chem & Mat Engn, Key Lab Synthet & Biol Colloids, Minist Educ, Wuxi 214122, Peoples R China

[2] Jiangnan Univ, State Key Lab Food Sci & Technol, Wuxi, Peoples R China

来源：

JOURNAL OF THE CHINESE CHEMICAL SOCIETY | 2019年 / 66卷 / 12期

关键词：

2-propanol; catalytic transfer hydrogenation; furfural; furfuryl alcohol; Ni-Fe (3; 1) LDH;

D O I：

10.1002/jccs.201800477

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Layered double hydroxides (LDHs) and their derivatives have been reported to be widely used as heterogeneous catalysts in various reactions. Herein, Ni-Fe LDHs with the controlled Ni/Fe molar ratios (2:1, 3:1, 4:1) were synthesized via an easy hydrothermal method, which were used to catalyze the selective reduction of biomass-derived furfural into furfuryl alcohol using 2-propanol as a H-donor under autogenous pressure and characterized using FT-IR, XRD, TGA, BET, SEM, NH3-TPD, and CO2-TPD. It was found that the LDH with a Ni/Fe molar ratio of 3:1 demonstrated the best catalytic activity among the LDHs with different Ni/Fe molar ratios, which showed 97.0% conversion of furfural and 90.2% yield of furfuryl alcohol at 140 degrees C for 5 hr. This was attributable to the synergistic effect of acidic sites and basic sites of the catalyst.

引用

页码：1610 / 1618

页数：9

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