Temperature dependent magnetic characterisation of core/shell Fe80Rh20 nanoparticles

被引:7
作者
Trunova, A. V. [1 ]
Lindner, J. [1 ]
Meckenstock, R. [1 ]
Spasova, M. [1 ]
Farle, M. [1 ]
Ciuculescu, D. [2 ]
Amiens, C. [2 ]
Chaudret, B. [2 ]
Respaud, M. [3 ]
机构
[1] Univ Duisburg Essen, Fachbereich Phys, Expt Phys AG Farle, D-47048 Duisburg, Germany
[2] Chim Coordinat Lab, F-31007 Toulouse 04, France
[3] INSA, LPCNO, F-31077 Toulouse 04, France
关键词
Nanoparticle; Ferromagnetic resonance; Anisotropy field; CORE;
D O I
10.1016/j.jmmm.2009.06.083
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Oxide free core-shell Fe80Rh20 nanoparticles with an average diameter of about 2 nm were wet-chemically synthesised with two different morphologies: either with Rh-rich or an Fe-rich core. The magnetic properties of these nanoparticles were investigated between 5 and 290 K by ferromagnetic resonance and superconducting quantum interference device magnetometry. The magnetic anisotropy field varied by a factor of 2 in this temperature range. The nanoparticles with Rh-rich core were found to have a higher anisotropy field of B-A = 0.214T at 5 K as compared to the nanoparticles with Fe-rich core (B-A = 0.169 T). Multifrequency ferromagnetic resonance (4-24 GHz) was used to determine the g-factor. It was determined that the g-factor of nanoparticles with Fe-rich core is higher (g = 2.08) compared to nanoparticles with Rh-rich core g = 2.06, being close to the value for iron bulk. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:3502 / 3506
页数:5
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