New metal complexes derived from 1-N-(6-nitrobenzimidazole-1-carbonylmethyl)-4-(alpha-naphthyl)-3-thiosemicarbazide

被引：0

作者：

Xu, PF

Xu, ZG

Wu, SZ

机构：

[1] LANZHOU MED COLL,LANZHOU 730000,PEOPLES R CHINA

[2] MMR,CENT RES INST BLDG & CONSTRUCT,BEIJING 100088,PEOPLES R CHINA

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1996年 / 26卷 / 01期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and characterization of Mn(II), Cu(II), Co(II), Ni(II), Pb (II) UO2 (VI) complexes of the new Ligand 1-N-(6-nitrobenzimidazole-1-carbonylmethyl)- 4-(alpha-naphthyl)-3-thiosemicarbazide (NBNMS) is reported. Infrared spectral data show that NBNMS behaves as a tetradentate Ligand involving the carbonyl and thiocarbonyl groups in conjunction with the adjacent nitrogen atoms (C = N groups). Each ligand bridges to two metal centers. This result in polymers that grow through consecutive ligand-metal linkages for all but UO2(VI). in contrast, NBNMS acts as a monobasic tridentate ligand with UO2(VI).

引用

页码：11 / 19

页数：9

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