Encapsulation of Sn@carbon Nanoparticles in Bamboo-like Hollow Carbon Nanofibers as an Anode Material in Lithium-Based Batteries

被引:538
作者
Yu, Yan [1 ]
Gu, Lin [2 ]
Wang, Chunlei [3 ]
Dhanabalan, Abirami [3 ]
van Aken, Peter A. [2 ]
Maier, Joachim [1 ]
机构
[1] Max Planck Inst Solid State Res, D-70569 Stuttgart, Germany
[2] Max Planck Inst Met Res, Stuttgart Ctr Electron Microscopy, D-70569 Stuttgart, Germany
[3] Florida Int Univ, Dept Mech & Mat Engn, Miami, FL 33174 USA
关键词
electrochemistry; electrospinning; lithium; tin; ION BATTERIES; ELECTROCHEMICAL PERFORMANCE; SECONDARY BATTERIES; TIN-NANOPARTICLES; HIGH-CAPACITY; STORAGE; NANOTUBES; ELECTRODE; SPHERES; COMPOSITES;
D O I
10.1002/anie.200901723
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Carbon-coated Sn nanoparticles in carbon nanofibers (see image) were fabricated by pyrolysis of coaxially electrospun nanofibers as an anode material for Li-ion batteries. The significantly improved electrochemical performance of such an electrode is believed to result from the unique nanostructure consisting of a thin carbon shell around tin nanoparticles, which are further encapsulated in hollow carbon nanofibers. © 2009 Wiley-VCH Verlag GmbH & Co. KCaA.
引用
收藏
页码:6485 / 6489
页数:5
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