共 3 条
Subtle media effects on formation of unique eclipsed vs staggered double chains: 1D silver(I) coordination polymers bearing C3-tridentate ligand
被引:1
|作者:
Kim, Euni
[1
]
Lee, Haeri
[1
]
Noh, Tae Hwan
[1
]
Lee, Young-A
[2
]
Jung, Ok-Sang
[1
]
机构:
[1] Pusan Natl Univ, Dept Chem, Pusan 609735, South Korea
[2] Chonbuk Natl Univ, Dept Chem, Jeonju 561756, South Korea
基金:
新加坡国家研究基金会;
关键词:
Anion exchangeability;
Eclipsed and staggered double chains;
Media effects;
Photoluminescence;
N,N ',N ''-tris(2-pyridinylethyl)-1,3,5-benzenetricarboxamide;
ANION-RESPONSIVE LUMINESCENCE;
STRUCTURAL-PROPERTIES;
METAL;
DESIGN;
CONSTRUCTION;
SEPARATION;
FRAMEWORK;
ARCHITECTURE;
COPPER(II);
COMPLEXES;
D O I:
10.1016/j.inoche.2014.05.006
中图分类号:
O61 [无机化学];
学科分类号:
070301 ;
081704 ;
摘要:
Self-assembly of AgX (X- = ClO4- and PF6-) with a C-3-tridentate ligand in EtOH/CH2Cl2 affords a ligand-eclipsed double chain whereas the cognate reaction in H2O/MeOH produces a ligand-staggered chain consisting of alternate cyclic and bridging moieties. The anion exchangeability and photoluminescence properties are significantly affected by the different skeletal structures. (C) 2014 Elsevier B.V. All rights reserved.
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页码:81 / 84
页数:4
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